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Effect of lithium boron oxide glass coating on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2

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Abstract

The effect of the lithium boron oxide glass coating on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2 has been investigated via solution method. The morphology, structure, and electrochemical properties of the bare and coated LiNi1/3Co1/3Mn1/3O2 are characterized by scanning electron microscopy, X-ray diffraction, electrochemical impedance spectroscopy, and charge–discharge tests. The results showed that the lattice structure of LiNi1/3Co1/3Mn1/3O2 is not changed after coating. The coating sample shows good high-rate discharge performance (148 mAh g−1 at 5.0 C rate) and cycling stability even at high temperature (with the capacities retention about 99% and 87% at room and elevated temperature after 50 cycles). The Li+ diffusion coefficient is also largely improved, while the charge transfer resistance, side reactions within cell, and the erosion of Hydrofluoric Acid all reduced. Consequently, the good electrochemical performances are obtained.

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Authors and Affiliations

  1. Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi, Xinjiang, 830011, China

    Junqing Dou, Xueya Kang, Tuerdi Wumaier, Hongwei Yu, Ning Hua, Ying Han & Guoqing Xu

  2. Graduate University of Chinese Academy of Sciences, Beijing, 100049, China

    Junqing Dou

  3. Xinjiang Key Laboratories of Electronic Information Materials and Devices, Urumqi, Xinjiang, 830011, China

    Junqing Dou, Xueya Kang, Tuerdi Wumaier, Ning Hua, Ying Han & Guoqing Xu

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  1. Junqing Dou
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  2. Xueya Kang
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  3. Tuerdi Wumaier
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  4. Hongwei Yu
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  5. Ning Hua
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  6. Ying Han
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  7. Guoqing Xu
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Correspondence to Xueya Kang.

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Dou, J., Kang, X., Wumaier, T. et al. Effect of lithium boron oxide glass coating on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2 . J Solid State Electrochem 16, 1481–1486 (2012). https://doi.org/10.1007/s10008-011-1550-1

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  • DOI: https://doi.org/10.1007/s10008-011-1550-1

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