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The hemoglobin-modified electrode with chitosan/Fe3O4 nanocomposite for the detection of trichloroacetic acid

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Abstract

A hemoglobin (Hb)-modified electrode based on chitosan/Fe3O4 nanocomposite coated glassy carbon has been constructed for trichloroacetic acid (TCA) detection. The structure of chitosan/Fe3O4 nanocomposite was investigated using energy-dispersive X-ray analysis (EDS) and X-ray diffraction (XRD) patterns. The electron transfer rate constant (k s) of Hb was estimated for as high as 3.12 s−1. The immobilized Hb exhibited excellent electro-catalytic activity toward the reduction of TCA. The response current regressed to the concentration of TCA within the range of 5.70 μM to 205 μM with a detection limit of 1.9 μM (S/N = 3).

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Grant numbers 21475070; 21175075), the Natural Science Foundation of Jiangsu Province (Grant number BK2011047), and the Universities Natural Science Foundation of Jiangsu Province (Grant number 12KJD150010).

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Authors and Affiliations

  1. Institute of Analytical Chemistry, Soochow University, Suzhou, 215123, People’s Republic of China

    Yuan-Hong Wang & Yi-Feng Tu

  2. Center of Analysis and Testing, School of Public Health, Institute of Analytical Chemistry for Life Science, Nantong University, Nantong, 226019, People’s Republic of China

    Yuan-Hong Wang, Chun-Mei Yu & Hai-Ying Gu

  3. Xinglin College, Institute of Analytical Chemistry for Life Science, Nantong University, Nantong, 226019, People’s Republic of China

    Hai-Ying Gu

Authors
  1. Yuan-Hong Wang
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  2. Chun-Mei Yu
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Correspondence to Hai-Ying Gu or Yi-Feng Tu.

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Wang, YH., Yu, CM., Gu, HY. et al. The hemoglobin-modified electrode with chitosan/Fe3O4 nanocomposite for the detection of trichloroacetic acid. J Solid State Electrochem 20, 1337–1344 (2016). https://doi.org/10.1007/s10008-015-3097-z

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  • DOI: https://doi.org/10.1007/s10008-015-3097-z

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