Abstract
Composite Li10SnP2S12 (LSPS)/polyethylene oxide (PEO) films, containing 25 to 50 % polymer, were electrophoretically deposited from acetone-based suspension and tested as possible candidates for polysulfide barriers in Li/S batteries. It was found by XRD and XPS tests that saturation of composite films by LiI salt, followed by prolonged annealing at 90 °C, diminishes the crystallinity of neat LSPS and results in the formation of a novel composite Li10+xIxSnP2S12 (LISPS)/P(EO)3/LiI solid electrolyte (x < 1). The high room-temperature ion conductivity of amorphous sulfide Li10+xIxSnP2S12 (0.1–0.3 mS cm−1) is restricted by slow ion transport via the polymer electrolyte (PE) imbedded in ceramics and grain boundaries between the PE and sulfide. Increase in polymer content and temperature improves total ion transport in the LISPS/PEO system. Conformal EPD coating of sulfur and lithium sulfide cathodes by the developed composite electrolyte increased the reversible capacity and Faradaic efficiency of the Li/S and Li/Li2S cells and enabled their operation at 60 °C.
Similar content being viewed by others
References
Nole DA, Moss V (1970) US Pat 3:532–543
Rauh RD, Abraham KM, Pearson GF, Surprenant JK, Brummer SB (1979) J Electrochem Soc 126:523–527
Yamin H, Peled E (1983) J Power Sources 9:281–287
Ji X, Lee KT, Nazar LF (2009) Nat Mater 8:500–506
Evers S, Nazar LF (2013) Acc Chem Res 46:1135–1143
Lai C, Gao XP, Zhang B, Yan TY, Zhou Z (2009) J Phys Chem C 113:4712–4716
Liang C, Dudney NJ, Howe JY (2009) Chem Mater 21:4724–4730
Song MK, Zhang Y, Cairns EJ (2013) Nano Lett 13:5891–5899
Wu F, Magasinskia A, Yushin G (2014) J Mater Chem A 2:6064–6070
Zheng Y, Yang JJ (2011) Cha, Hong SS, cui Y. Nano Lett 11:4462–4467
Hayashi OT, Mizuno F, Tadanaga K, Tatsumisago M (2003) Electrochem Commun 5:701–705
Yu X, Xie J, Yang J, Wang K (2004) J Power Sources 132:181–186
Machidaa N, Kobayashia K, Nishikawaa Y, Shigematsu T (2004) Solid State Ionics 175:247–250
Scrosati HJ (2010) B Adv Mater 22:5198–5201
Xin S, Guo YG, Wan LJ (2012) Acc Chem Res 45:1759–1769
Wang H, Yang Y, Liang Y, Robinson JT, Li Y, Jackson A, Cui Y, Dai H (2011) Nano Lett 11:2644–2647
Li W, Zhang Q, Zheng G, Seh ZW, Yao H, Cui Y (2013) Nano Lett 13:5534
Ji X, Evers S, Black R, Nazar LF (2011) Nat Commun 325:293
Su YS, Manthiram A (2012) Chem Commun 48:8817–8819
Xiao L, Cao Y, Xiao J, Schwenzer B, Engelhard MH, Saraf LV, Nie Z, Exarhos GJ, Liu J (2012) Adv Mater 24:1176–1181
Visco S J, Katz BD, Nimon YS, De Jonghe LC (2012) PolyPlus Battery Company, U.S. Patent 8293398
Lu Y, Goodenough JB, Kim YJ (2011) Am Chem Soc 133:5756–5759
Li W, Hicks-Garner J, Wang J, Liu J, Gross AF, Sherman E, Graetz J, Vajo JJ, Liu P (2014) Chem Mater 26:3403–3410
Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM (2012) Nat Mater 11:19–29
Park JW, Ueno K, Tachikawa N, Dokko K, Watanabe M (2013) J Phys Chem C:20531
Salitra G, Markevich E, Rosenman A, Talyosef Y, Aurbach D, Garsuch A (2014) ChemElectroChem 319:1492
Bron P, Johansson S, Zick K, Schmedt auf der Günne J, Dehnen S (2013) J Am Chem Soc 135:15694–15697
Nagao M, Hayashi A, Tatsumisago M (2012) J Mater Chem 22:10015–10020
Kitaura H, Hayashi A, Ohtomo T, Hama S, Tatsumisago M (2011) J Mater Chem 21:118
Liu D, Zhu W, Feng Z, Guerfi A, Vijh A, Zaghib K (2016) Mater Sci Eng B. doi:10.1016/j.mseb.2016.03.005
Sakuda A, Hayashi A, Ohtomo T, Hama S, Tatsumisago M (2010) Electrochem Solid-State Lett 13:A73–A75
Hayashi A, Yamashita H, Tatsumisago M, Minami T (2002) Solid State Ionics 148:381–389
Rangasamy E, Liu Z, Gobet M, Pilar K, Sahu G, Zhou W, Wu H, Greenbaum S, Liang C (2015) J Am Chem Soc 137:1384–1387
Ohshima H, Ohki S (1985) Biophys J 47:673
Zhulina EB, Borisov OV (2011) Langmuir 27:10615
Blanga R, Burstein L, Berman M, Greenbaum SG, Golodnitsky D (2015) J Electrochem Soc 162:D3084–D3089
Armand M (1983) Solid State Ionics 9-10:745–754
Kuhn A, Gerbig O, Zhu C, Falkenberg F, Maier J, Lotsch BW (2014) Phys Chem Chem Phys 16:14669
Blanga R, Berman M, Biton M, Tariq F, Yufit V, Gladkich A, Greenbaum SG, Brandon N, Golodnitsky D (2016) Electrochim Acta 208:71–79
Martin-Vosshage D, Chowdari BVR (1995) Electrochim Acta 13-14(40):2109–2114
Graf N, Yegen E, Gross T, Lippitz A, Weigel W, Krakert S, Terfort A, Unger W (2009) Surf Sci 603:2849–2860
Beamson G, Briggs D (1992) High resolution XPS of organic polymers—the Scienta ESCA300 Database, Wiley Interscience, Appendices 3.1 and 3.2
Ota H, Sakata Y, Wang X, Sasahara J, Yasukawa E (2004) J Electrochem Soc 151:A437–A446
NIST X-ray photoelectron spectroscopy database, NIST standard reference database 20, version 4.1 http://srdata.nist.gov/xps/Version_his.aspx
Acknowledgments
This work has been funded by the Israel Academy of Science, Grant 2049/14.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Blanga, R., Goor, M., Burstein, L. et al. The search for a solid electrolyte, as a polysulfide barrier, for lithium/sulfur batteries. J Solid State Electrochem 20, 3393–3404 (2016). https://doi.org/10.1007/s10008-016-3303-7
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-016-3303-7