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Effects of alumina nanoparticles in waste chicken fat biodiesel on the operating characteristics of a compression ignition engine

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Abstract

An experimental investigation was carried out to study the performance, emissions and combustion characteristics of a compression ignition (CI) engine fuelled with waste chicken fat biodiesel with alumina nanoparticles as an additive. The disposal of waste chicken creates environmental pollution, hence it is decided to extract oil from the waste chicken fat and produce biodiesel through transesterification process. As the chicken fat contains 13.6 % free fatty acid (FFA), a pre-treatment process was carried out using Ferric sulphate as a catalyst in order to reduce the FFA content less than 1 % to prevent soap formation during the process. Potassium hydroxide was used as catalysts for the effective conversion of triglycerides of waste chicken fat into methyl ester. Various diesel–biodiesel–alumina blends were prepared by varying the biodiesel proportions of 20 and 40 % by volume and 25 and 50 ppm of alumina nanoparticles to study its operating characteristics on a computerized single cylinder, constant speed CI engine. Aluminium oxide (Al2O3) nanoparticles were used as fuel born catalyst in order to enhance the combustion characteristics and reduce the harmful emissions. The engine test results showed less improvement in brake thermal efficiency and significant reduction on the hydrocarbons and carbon monoxide emissions. However, higher nitrogen oxide emissions were recorded due to the increase in combustion temperature as the nanoparticles enhanced the surface area to volume ratio which improves the thermal conductivity of the fuel blend resulted in improved combustion. Smoke reduction of 52.8 % was observed in B40 fuel blend with 50 ppm alumina nanoparticles under full load conditions.

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Abbreviations

Al2O3 :

Aluminium oxide

B20Al25:

Diesel 80 % + Biodiesel 20 % + Alumina nanoparticles 25 ppm

B20Al50:

Diesel 80 % + Biodiesel 20 % + Alumina nanoparticles 50 ppm

B40Al25:

Diesel 60 % + Biodiesel 40 % + Alumina nanoparticles 25 ppm

B40Al50:

Diesel 60 % + Biodiesel 40 % + Alumina nanoparticles 50 ppm

bmep:

Brake mean effective pressure

BSFC:

Brake specific fuel consumption

BTE:

Brake thermal efficiency

CI:

Compression ignition

CNT:

Carbon nanotubes

CO:

Carbon monoxide

FFA:

Free fatty acid

HC:

Hydrocarbon

HRR:

Heat release rate

ID:

Ignition delay

NOx :

Nitrogen oxides

PM:

Particulate matter

ppm:

particles per million

RoPR:

Rate of pressure raise

TDC:

Top dead center

WCF:

Waste chicken fat

WCFME:

Waste chicken fat methyl ester

References

  • Adaileh WM, AlQdah KS (2012) Performance of diesel engine fuelled by a biodiesel extracted from a waste cocking oil. Energy Procedia 18:1317–1334

    Article  CAS  Google Scholar 

  • An H, Yang WM, Chou SK, Chua KJ (2012) Combustion and emissions characteristics of diesel engine fueled by biodiesel at partial load conditions. Appl Energy 99:363–371

    Article  CAS  Google Scholar 

  • Anand R, Kannan GR, Nagarajan S, Velmathi S (2010) Performance emission and combustion characteristics of a diesel engine fueled with biodiesel produced from waste cooking oil. SAE Transactions Paper No: 20100478

  • Arul Mozhi Selvan V, Anand RB, Udayakumar M (2009a) Effects of cerium oxide nanoparticle addition in diesel and diesel-biodiesel-ethanol blends on the performance and emission characteristics of a CI engine. ARPN J Eng Appl Sci 4:1–6

    Google Scholar 

  • Arul Mozhi Selvan V, Anand RB, Udayakumar M (2009) Stability, performance and emission characteristics of diesel-ethanol blend with castor oil as additive in variable compression ratio engine. SAE Transactions, Paper No: 20097120

  • Basha JS, Anand RB (2011) An experimental study in a CI engine using nanoadditive blended water–diesel emulsion fuel. Int J Green Energy 8(3):332–348

    Article  CAS  Google Scholar 

  • Basha JS, Anand RB (2012) Effects of nanoparticle additive in the water–diesel emulsion fuel on the performance, emission and combustion characteristics of a diesel engine. Int J Veh Des 59:164–181

    Article  Google Scholar 

  • Bhatti HN, Hanif MA, Qasim M, ur Rehman Ata (2008) Biodiesel production from waste tallow. Fuel 87:2961–2966

    Article  CAS  Google Scholar 

  • Biona JBM, Licauco J (2009) Performance, smoke characteristics and economics of pre-heated used vegetable oil utilization in Philippine public utility jeepneys. Clean Technol Environ Policy 11:239–245

    Article  CAS  Google Scholar 

  • Bittle JA, Knight BM, Jacobs TJ (2010) Interesting behavior of biodiesel ignition delay and combustion duration. Energy Fuels 24:4166–4177

  • Dale N (1992) True metabolizable energy of feather meal. Journal of Appl Poul Res 1:331–334

    Article  Google Scholar 

  • Encinar JM, Sanchez N, Martinez G, Garcia L (2011) Study of biodiesel production from animal fats with high free fatty acid content. Bioresour Technol 102:10907–10914

    Article  CAS  Google Scholar 

  • Flemming Cassee R, Campbell Arezoo, John Boere AF, Steven McLean G, Duffin Rodger, Krystek Petra, Gosens Ilse, Mark Miller R (2012) The biological effects of subacute inhalation of diesel exhaust following addition of cerium oxide nanoparticles in atherosclerosis-prone mice. Environ Res 115:1–10

    Article  Google Scholar 

  • Guru Metin, Koca A, Can O, Cinar C, Sahin F (2010) Biodiesel production from waste chicken fat based sources and evaluation with Mg based additive in a diesel engine. Renew Energy 35:637–643

    Article  CAS  Google Scholar 

  • Heywood John B (1988) Internal combustion engine fundamentals. Tata McGraw-Hill, USA

    Google Scholar 

  • Jindal S, Goyal K (2012) Evaluation of performance and emissions of Hibiscus cannabinus (Ambadi) seed oil biodiesel. Clean Technol Environ Policy 14:633–639

    Article  CAS  Google Scholar 

  • Jones M, LI CH, Afjeh A, Peterson GP (2011) Experimental study of combustion characteristics of nanoscale metal and metal oxide additives in biofuel (ethanol). Nanoscale Res Lett 6:246. doi:10.1186/1556-276X-6-246

    Article  Google Scholar 

  • Jung Heejung, David Kittelson B, Michael Zachariah R (2005) The influence of a cerium additive on ultrafine diesel particle emissions and kinetics of oxidation. Combust Flame 142:276–288

    Article  CAS  Google Scholar 

  • Kannan GR, Karvembu R, Anand R (2011) Effect of metal based additive on performance emission and combustion characteristics of diesel engine fuelled with biodiesel. Appl Energy 88:3694–3703

    Article  CAS  Google Scholar 

  • Lei Zhu Cheung CS, Zhang WG, Huang Zhen (2011) Combustion, performance and emission characteristics of a DI diesel engine fueled with ethanol–biodiesel blends. Fuel 90:1743–1750

    Article  Google Scholar 

  • Marulanda VF, Anitescu G, Tavlarides LL (2010) Biodiesel fuels through a continuous flow process of chicken fat supercritical transesterification. Energy Fuels 24:253–260

    Article  CAS  Google Scholar 

  • Mustafa Canakci, Jon Van Gerpen (2001) A Pilot Plant to Produce Biodiesel from High Free Fatty Acid Feedstocks. The American Society of Agricultural Engineers (ASAE) Paper Number: 01-6049, 1–19

  • Naresh Kumar Gurusala, Arul Mozhi Selvan V, Ajay Balan, Shreyas Athreya “Optimization of waste chicken fat pre-treatment process using response surface methodology”, SAE Tran. Paper No: 20139131

  • Oner C, Altun S (2009) Biodiesel production from inedible animal tallow and an experimental investigation of its use as alternative fuel in a direct injection diesel engine. Appl Energy 86:2114–2120

    Article  CAS  Google Scholar 

  • Rahimi H, Ghobadian B, Yusaf T, Najifi Gholamhasan, khatamifar M (2009) Diesterol: an environmental-friendly IC engine fuel. Renew Energy 34:335–342

    Article  CAS  Google Scholar 

  • Rajesh Mehta, Nambiar RG (2007) The poultry industry in India. FAO conference on poultry in the 21st century, Bangkok

  • Resitoglu IA, Altinisik K, Keskin A (2014) The pollutant emissions from diesel-engine vehicles and exhaust aftertreatment systems. Clean Technol Environ Policy. doi:10.1007/s10098-014-0793-9

    Google Scholar 

  • Rutz D, Janssen R (2007) Biofuel technology handbook. WIP Renewable Energies, Germany

    Google Scholar 

  • Sahoo PK, Das LM, Babu MKG, Arora P, Singh VP, Kumar NR, Varyani TS (2009) Comparative evaluation of performance and emission characteristics of jatropha, karanja and polanga based biodiesel as fuel in a tractor engine. Fuel 88:1698–1707

    Article  CAS  Google Scholar 

  • Sajith V, Sobhan CB, Peterson GP (2010) Experimental investigations on the effects of cerium oxide nanoparticle fuel additives on biodiesel. Adv Mech Eng. doi:10.1155/2010/581407

  • Shafii MB, Deneshvar F, Jahani N, Mobini K (2011) Effect of ferrofluid on the performance and emission patterns of a four-strokee diesel engine. Adv Mech Eng. doi:10.1155/2011/529049

  • Yetter RA, Risha GA, Son SF (2009) Metal particle combustion and nanotechnology. Proc Combust Inst 32:1819–1838

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful to Dr. Srinivasan Sundarrajan, Director, National Institute of Technology, Tiruchirapalli for granting permission to establish Advanced I.C. Engines Research Laboratory in the Mechanical Engineering Department with modern computerized experimental facilities to the international standards. The authors are thankful to Dr. R.B. Anand and Mr. Dominic for their continuous support and encouragement in conduction the experiments. Also special thanks are given to Mr. Palanisamy, Mr. Kaliyaperumal and Mr. Durairaj for their help rendered during experimentation.

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Correspondence to V Arul Mozhi Selvan.

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Gurusala, N.K., Selvan, V.A.M. Effects of alumina nanoparticles in waste chicken fat biodiesel on the operating characteristics of a compression ignition engine. Clean Techn Environ Policy 17, 681–692 (2015). https://doi.org/10.1007/s10098-014-0825-5

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