Abstract
Nanocomposites of polyaniline (PANI) and the macrocycle thiacalix[4]arene tetra sulfonate (TCAS) were successfully synthesized in feed ratios of 1:0.25, 1:0.50 and 1:0.75 by three prevail synthetic methods, i.e. in situ polymerization, emulsion polymerization and solution casting technique. The structures of the nanocomposites were confirmed by FTIR, UV-Vis, XRD, SEM, and TEM techniques. The conductivity was measured by a four probe method. The conductivity was recorded to be as high as 105 × 10−2 S·cm−1 for the nanocomposite with a nanometer size structure and homogeneously distributed morphology. The electroactivity of the nanocomposites was approved by cyclic voltammetry (CV) and impedance spectroscopy technique (EIS). The antioxidant ability and thermal property of the composites were further studied. Preliminary studies have evidenced the production of conductive nanocomposites with good thermal property and relatively good solubility in N-methyl 2-pyrrolidone (NMP), with the antioxidant activity reaching up to 80%.
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Toshiam, N. and Hara, S., Prog. Polym. Sci., 1995, 20: 155
Genies, E.M., Boyle, A., Lapkowski, M. and Tsintavis, C., Synthetic Met., 1990, 36: 139
Bhattacharya, A. and De, A., Prog. Solid St. Chem., 1996, 24: 141
Stejskal, J., Sapurina, I. and Trchova, M., Prog. Polym. Sci., 2010, 35: 1420
Gutsche, C.D., Alam, F., Iqbal, M., Mangiafico, T., Nam, K.C., Rogers, J. and See, K.A., J. Inclus. Phenom. Mol., 1998, 7: 61
Lakouraj, M.M. and Tashakkorian, H., J. Macromol. Sci. Pure, 2012, 49: 806
Lakouraj, M.M. and Tashakkorian, H., J. Macromol. Sci. Pure, 2013, 50: 310
Davey, J.M., Too, C.O., Ralph, S.F., Kane-Maguire, L.A.P. and Wallace, G.G., Macromolecules, 2000, 33: 7044
Grigoras, M., Catargiu, A.M. and Tudorache, F., J. Appl. Polym. Sci., 2013, 127: 2796
Catargiu, A. and Grigoras, M., Acta Chem. Iasi, 2011, 19: 81
Lhotak, P., Eur. J. Org. Chem., 2004, 8: 1675
Kajiwara, T., Iki, N. and Yamashita, M., Coordin. Chem. Rev., 2007, 251: 1734
Cho, J., Sato, S., Takeoka, S. and Tsuchida, E., Macromolecules, 2001, 34: 2751
Evtugyn, G.A., Belyakova, S.V., Shamagsumova, R.V., Savelev, A.A., Ivanov, A.N., Stoikova, E.E., Dolgova, N.N., Stoikov, I.I., Antipin, I.S. and Budnikov, H.C., Talanta, 2010, 82: 613
Evtugyn, G.A., Shamagsumova, R.V., Stoikova, E.E., Sitdikov, R.R., Stoikov, I.I., Budnikov, H.C., Ivanov, A.N. and Antipin, I.S., Electroanal., 2011, 23: 1081
Evtugyn, G.A., Stoikov, I.I., Belyakova, S.V., Shamagsumova, R.V., Stoikova, E.E., Zhukov, A.Yu., Antipin, I.S. and Budnikov, H.C., Talanta, 2007, 71: 1720
Yuan, D., Zhu, W.X., Ma, S. and Yan, X., J. Mol. Struct., 2002, 616: 241
Guo, Q., Zhu, W., Dong, S., Ma, S. and Yan, X., J. Mol. Struct., 2003, 650: 159
Yamada, M., Kondo, Y. and Hamada, F., Int. J. Soc. Mater. Eng. Resour., 2008, 15: 50
Evtugyn, G.A., Stoikov, I.I., Belyakova, S.V., Stoikova, E.E., Shamagsumova, R.V., Zhukov, A.Yu., Antipin, I.S. and Budnikov, H.C., Talanta, 2008, 76: 441
Pud, A., Ogurtsov, N., Korzhenko, A. and Shapoval, G., Prog. Polym. Sci., 2003, 28: 1701
Anand, J., Palaniappan, S. and Sathyanarayana, D.N., Prog. Polym. Sci., 1993, 23: 993
Osterholm, J.E., Cao, Y., Klavetter, F. and Smith, P., Polymer, 1994, 35: 2902
Soares, J.R., Dinis, T.C.P., Cunha, A.P. and Almeida, L.M., Free. Radical. Res., 1997, 26: 469
Huang, G., Ma, S., Zhao, X., Yang, X. and Ooi, K., Chem. Commun., 2009, 0: 331
Hu, X., Li, Y., Wang, Y., Li, X., Li, H., Liu, X. and Zhang, P., Desilation, 2010, 259: 76
Dallas, P., Stamopoulos, D., Boukos, N., Tzitzios, V., Niarchos, N. and Petridis, D., Polymer, 2007, 48: 3162
Bredas, J.L. and Street, G.B., Accounts Chem. Res., 1985, 18: 309
Pouget, J.P., Jdzefowiczt, M.E., Epstein, A.J., Tang, X. and MacDiarmid, A.G., Macromolecules, 1991, 24: 779
Kondawar, S.B., Deshpande, M.D. and Agrawal, S.P., Int. J. Compos. Mater., 2012, 2: 32
Jeon, H.J., Yi, S.C. and Oh, S.G., Biomaterials, 2003, 24: 4921
Moghadam, P.N. and Zareh, E.N., e-Polymers, 2010, 54: 1
Epstein, A.J., Ginder, J.M., Zhuo, F., Woo, H.S., Tanner, D.B., Richter, A.F., Angelopoulos, M., Huang, W.S. and MacDiarmid, A.G., Synth. Met., 1987, 21: 63
Huang, W.S. and MacDiarmid, A.G., Polymer, 1993, 34: 1833
Li, X.G., Kang, Y. and Huang, M.R., J. Comb. Chem., 2006, 8: 670
Yue, J., Wang, Z.H., Cromack, K.R., Epstein, A.J. and MacDiarmidl, A.G., J. Am. Chem. Soc., 1991, 113: 2665
Chen, S.A. and Hwang, G.W., J. Am. Chem. Soc., 1995, 117: 10055
Wei, X.L., Wang, Y.Z. Long, S.M. Bobeczko, C. and Epstein, A.J., J. Am. Chem. Soc., 1996, 118: 2545
Bard, A.J. and Faulkner, L.R. “Electrochemical Methods Fundamentals and Applications”, 2nd ed, John Wiley & Sons, Inc., New York, 2001, p. 226
Gupta, V. and Miura, N., Electrochem. Commun., 2005, 7: 995
Dong, B., He, B.L., Xu, C.L. and Li, H.L., Mat. Sci. Eng. B-Solid, 2007, 143: 7
Afzal, A.B., Akhtar, M.J., Nadeem, M. and Hassan, M.M., Curr. Appl. Phys., 2010, 10: 601
Consoli, G.M.L., Galante, E., Daquino, C., Granata, G., Cunsolo, F. and Geraci, C., Tetrahedron Lett., 2006, 47: 6611
Vovk, A.I., Shivanyuk, A.M., Bugas, R.V., Muzychka, O.V. and Melnyk, A.K., Bioorg. Med. Chem. Lett., 2009, 19: 1314
Patel, M.B., Modi, N.R., Raval, J.P. and Menon, S.K., Org. Biomol. Chem., 2012, 10: 1785
Odo, J., Kimura, A., Matsu-Ura, A., Ohnishi, Y., Sahki, Y., Yoshida, Y., Hayashi, K., Inoguchi, M. and Ueki, T., Chem. Pharm. Bull., 2010, 58: 1576
Jipa, S., Zaharescu, T., Setnescu, R., Setnescu, T., Dumitru, M., Gorghiu, L.M., Mihalcea, I. and Bumbac, M., Polym. Degrad. Stabil., 2003, 80: 203
Conklin, J.A., Huang, S., Huang, S., Wen, T. and Kaner, R.B., Macromolecules, 1995, 28: 6522
Conklin, J.A., Anderson, M.R., Reiss, H. and Kaner, R.B., J. Phys. Chem, 1996, 100: 8425
Lee, B.H., Kim, H.J. and Yang, H.S., Curr. Appl. Phys., 2012, 12: 75
Alves, W.F., Venancio, E.C., Leite, F.L., Kanda, D.H.F., Malmonge, L.F., Malmonge, J.A. and Mattoso, L.H.C., Thermochim. Acta, 2010, 502: 43
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Norouzian, RS., Lakouraj, M.M. & Zare, E.N. Novel conductive PANI/hydrophilic thiacalix[4]arene nanocomposites: synthesis, characterization and investigation of properties. Chin J Polym Sci 32, 218–229 (2014). https://doi.org/10.1007/s10118-014-1402-4
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DOI: https://doi.org/10.1007/s10118-014-1402-4