Skip to main content
SpringerLink
Log in

A System Map for the Ionic Liquid Stationary Phase 1,9-Di(3-vinylimidazolium)nonane Bis(trifluoromethylsulfonyl)imide

  • Original
  • Published:
Chromatographia Aims and scope Submit manuscript

Abstract

The solvation parameter model is used to characterize the retention properties of the ionic liquid stationary phase 1,9-di(3-vinylimidazolium)nonane bis(trifluoromethylsulfonyl)imide (SLB-IL100) over the temperature range 60–200 °C. The results are presented in the form of a system map comprising a continuous plot of the system constants of the solvation parameter model determined at 20 °C intervals as a function of column temperature. The ionic liquid stationary phase is a cohesive, polar solvent with significant hydrogen-bonding capability. It differs from polar siloxane-based and poly(ethylene glycol) stationary phases by being a moderate hydrogen-bond acid and is shown to possess separation properties that are not duplicated in a comprehensive database of system constants for commercially available open-tubular columns.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Poole CF, Poole SK (2002) J Chromatogr A 965:263–299

    Article  CAS  Google Scholar 

  2. Poole CF, Poole SK (2008) J Chromatogr A 1184:254–280

    Article  CAS  Google Scholar 

  3. Poole CF (ed) (2012) Gas chromatography. Elsevier, Amsterdam

    Google Scholar 

  4. Atapattu SN, Poole CF (2008) J Chromatogr A 1185:305–309

    Article  CAS  Google Scholar 

  5. Atapattu SN, Eggers K, Poole CF, Kiridena W, Koziol WW (2009) J Chromatogr A 1216:1640–1649

    Article  CAS  Google Scholar 

  6. Atapattu SN, Poole CF (2008) J Chromatogr A 1195:136–145

    Article  CAS  Google Scholar 

  7. Karunasekara T, Poole CF (2012) J Chromatogr A 1266:124–130

    Article  CAS  Google Scholar 

  8. Yao C, Anderson JL (2008) J Chromatogr A 1216:1658–1712

    Article  Google Scholar 

  9. Poole CF, Poole SK (2011) J Sep Sci 34:888–900

    Article  CAS  Google Scholar 

  10. Poole CF, Lenca N (2014) J Chromatogr A 1357:87–109

    Article  CAS  Google Scholar 

  11. Anderson JL, Armstrong DW (2005) Anal Chem 77:6453–6462

    Article  CAS  Google Scholar 

  12. Qi M, Armstrong DW (2007) Anal Bioanal Chem 388:889–899

    Article  CAS  Google Scholar 

  13. Ragonese C, Sciarrone D, Tranchida, Dugo P, Mondello L (2012) J Chromatogr A 1255:130–144

    Article  CAS  Google Scholar 

  14. Abraham MH, Poole CF, Poole SK (1999) J Chromatogr A 842:79–114

    Article  CAS  Google Scholar 

  15. Vitha M, Carr PW (2006) J Chromatogr A 1126:143–194

    Article  CAS  Google Scholar 

  16. Poole CF, Atapattu SN, Poole SK, Bell AK (2009) Anal Chim Acta 652:32–53

    Article  CAS  Google Scholar 

  17. Abraham MH, Ibrahim A, Zissimos AM (2004) J Chromatogr A 1037:29–47

    Article  CAS  Google Scholar 

  18. Poole CF, Ariyasena TC, Lenca N (2013) J Chromatogr A 1317:85–104

    Article  CAS  Google Scholar 

  19. Rodriguez-Sanchez S, Galindo-Iranzo P, Soria AC, Sanz ML, Quintanilla-Lopez JE, Lebron-Aguilar R (2014) J Chromatogr A 1326:96–102

    Article  CAS  Google Scholar 

  20. Livingstone D (2009) A practical guide to scientific data analysis. Wiley, New York, pp 58–73

    Book  Google Scholar 

  21. Xu Q, Su B, Luo X, Xing H, Bao Z, Yang Q, Yang Y, Ren O (2012) Anal Chem 84:9109–9115

    CAS  Google Scholar 

  22. Li Q, Poole CF (2000) Chromatographia 52:639–647

    Article  CAS  Google Scholar 

  23. Poole CF, Kollie TO (1993) Anal Chim Acta 282:1–17

    Article  CAS  Google Scholar 

  24. Poole CF, Poole SK (2009) J Chromatogr A 1216:1530–1550

    Article  CAS  Google Scholar 

  25. Kiridena W, Qian J, Koziol WW, Poole CF (2007) J Sep Sci 30:740–745

    Article  CAS  Google Scholar 

  26. Poole CF, Kiridena W, Nawas MI, Koziol WW (2002) J Sep Sci 25:749–759

    Article  CAS  Google Scholar 

  27. Martin SD, Poole CF, Abraham MH (1998) J Chromatogr A 805:217–235

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Rm. 185, Department of Chemistry, Wayne State University, Detroit, MI, 48202, USA

    Nicole Lenca & Colin F. Poole

Authors
  1. Nicole Lenca
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Colin F. Poole
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Colin F. Poole.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 21 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lenca, N., Poole, C.F. A System Map for the Ionic Liquid Stationary Phase 1,9-Di(3-vinylimidazolium)nonane Bis(trifluoromethylsulfonyl)imide. Chromatographia 78, 81–88 (2015). https://doi.org/10.1007/s10337-014-2790-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10337-014-2790-x

Keywords

Search

Navigation