Skip to main content
Log in

In-Situ Investigation of Resin Shrinkage in the Composite Manufacturing Environment

  • Published:
Applied Composite Materials Aims and scope Submit manuscript

Abstract

Cure shrinkage of the polymer matrix during the composite manufacturing process leads to residual stresses, which can adversely affect the structural integrity and dimensional stability of composite structures. In this paper, a novel approach is developed for measuring the resin shrinkage and strain evolution of an epoxy resin (EPON-862) in the composite manufacturing environment. The resin is cured in a custom designed autoclave with borosilicate viewports, while digital image correlation (DIC) is used to analyze the strain evolution throughout the cure cycle. These processing induced strains are correlated to the cure-state using differential scanning calorimetery (DSC). The different mechanisms involved in the polymer strain evolution during composite processing are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Data Availability

The data will be made available on request.

References

  1. Dusek, K.: Network formation in curing of epoxy resins. Adv. Polym. Sci. 78, 1–59 (1986). https://doi.org/10.1007/bfb0035356

    Article  CAS  Google Scholar 

  2. Wisnom, M.R., Gigliotti, M., Ersoy, N., Campbell, M., Potter, K.D.: Mechanisms generating residual stresses and distortion during manufacture of polymer-matrix composite structures. Compos. Part A Appl. Sci. Manuf. 37, 522–529 (2006). https://doi.org/10.1016/j.compositesa.2005.05.019

    Article  CAS  Google Scholar 

  3. Snow, A.W., Armistead, J.P.: A simple dilatometer for thermoset cure shrinkage and thermal expansion measurements. J. Appl. Polym. Sci. 52, 401–411 (1994). https://doi.org/10.1002/app.1994.070520305

    Article  CAS  Google Scholar 

  4. Shah, D.U., Schubel, P.J.: Evaluation of cure shrinkage measurement techniques for thermosetting resins. Polym. Test. 29, 629–639 (2010). https://doi.org/10.1016/j.polymertesting.2010.05.001

    Article  CAS  Google Scholar 

  5. Kravchenko, O.G., Kravchenko, S.G., Casares, A., Pipes, R.B.: Digital image correlation measurement of resin chemical and thermal shrinkage after gelation. J. Mater. Sci. 50, 5244–5252 (2015). https://doi.org/10.1007/s10853-015-9072-3

    Article  CAS  Google Scholar 

  6. EPON-862\Epikure W technical data sheet. https://www.miller-stephenson.com/wp-content/uploads/2016/08/W.pdf. Accessed 06 Jan 2021

  7. Yoneyama, S., Murasawa, G.: Digital image correlation. Exp. Mech. (2009)

    Google Scholar 

  8. Correlated solutions, https://www.correlatedsolutions.com/vibration-fatigue-module. Accessed 06 Jan 2021

  9. Hardis, R., Jessop, J.L.P., Peters, F.E., Kessler, M.R.: Cure kinetics characterization and monitoring of an epoxy resin using DSC, Raman spectroscopy, and DEA. Compos. Part A Appl. Sci. Manuf. 49, 100–108 (2013). https://doi.org/10.1016/j.compositesa.2013.01.021

    Article  CAS  Google Scholar 

  10. Fu, Y., Michopoulos, J.G., Song, J.H.: On investigating the thermomechanical properties of cross-linked epoxy via molecular dynamics analysis. Nanoscale Microscale Thermophys. Eng. 21, 8–25 (2017). https://doi.org/10.1080/15567265.2016.1263696

    Article  CAS  Google Scholar 

  11. Chava, S., Namilae, S.: In situ investigation of the kinematics of ply interfaces during composite manufacturing. J. Manuf. Sci. Eng. Trans. ASME. 143, 1–10 (2021). https://doi.org/10.1115/1.4047740

    Article  Google Scholar 

  12. Chava, S., Namilae, S.: Continuous Evolution of Processing Induced Residual Stresses in Composites: An In-situ Approach. In: Composites: Part A (In Print)

Download references

Acknowledgement

This work was funded by NSF AM contract number 2001038. We thank Dr Sandra Boetcher for access to DSC and Dr Marwan Alhaik for useful discussions.

Funding

This work was funded by NSF AM contract number 2001038.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sirish Namilae.

Ethics declarations

Conflict of Interest

The authors have no conflicts of interests to declare.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Motagi, S., Namilae, S. In-Situ Investigation of Resin Shrinkage in the Composite Manufacturing Environment. Appl Compos Mater 28, 651–657 (2021). https://doi.org/10.1007/s10443-021-09887-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10443-021-09887-x

Keywords

Navigation