Abstract
Spherical Pd nanoparticles (2–8 nm) were immobilized on the nanometer-scaled platelets of montmorillonite (MMT) by means of cation exchange of Pd2+ for Na+ followed by chemical reduction. The resulting Pd catalysts were readily dispersible in water and polar solvents. Polarity design and thus, variation of the dispersion behavior was achieved by subsequent organophilic MMT modification involving cation exchange with N-alkyl and N-perfluoroalkylethyl pyridinium cations. This allowed for easy catalyst dispersion in a wide range of organic solvents. According to characterization by TEM, EDXS, AAS and WAXS the nanoparticle formation did not destroy the superstructure of unmodified and organophilic MMT. Catalysts were applied to hydrogenation, Suzuki–Miyaura C–C coupling and fluorous biphase catalysis. The tunable dispersion behavior of MMT catalysts was successfully employed to guarantee easy catalyst recovery and recycling.
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References
Schlögl R, Abd Hamid SB (2004) Angew Chem Int Ed 43:1628
Grunes J, Zhu A, Somorjai GA (2003) Chem Commun 2257
Feldheim DL, Foss CA Jr (2001) Metal nanoparticles. Synthesis characterization and applications. Marcel Dekker, New York
Astruc D (ed) (2007) Nanoparticles and catalysis. Wiley–VCH, Weinheim, p 640
Hofmann U (1968) Angew Chem Int Ed 7:681
Hofmann U (1956) Angew Chem Int Ed 68:53
Hofmann U, Giese K (1939) Kolloid Z21
Vaccari A (1999) Appl Clay Sci 14:161
Cornélis A, Laszlo P (1985) Synthesis 909
Pinnavaia TJ (1983) Science 220:365
Balogh M, Laszlo P (1993) Organic chemistry using clays. Springer, New York
Choudary BM, Ravi Kumar K, Kantam ML (1991) J Catal 130:41
Choudary BM, Vasantha G, Sharma M, Bharathi P (1989) Angew Chem Int Ed 28:465
Ravi Kumar K, Choudary BM, Jamil Z, Thyagarajan G (1986) Chem Commun 130
Poyatos M, Márquez F, Peris E, Claver C, Fernandez E (2003) New J Chem 27:425
Varma RS, Naicker KP, Liesen PJ (1999) Tetrahedron Lett 40:2075
Ramchandani RK et al (1997) Chem Commun 2071
Crocker M, Buglass JG, Herold RHM (1993) Chem Mater 5:105
Papp S, Dékány I (2006) Colloid Polym Sci 284:1049
Papp S, Szücs A, Dékány I (2001) Solid State Ionics 141:169
Mastalir A, Király Z, Szollosi G, Bartók M (2001) Appl Catal A 213:133
Mastalir Á, Király Z, Szöllösi G, Bartók M (2000) J Catal 194:146
Király Z, Veisz B, Mastalir A, Rázga Z, Dékány I (1999) Chem Commun 1925
Király Z, Dékány I, Mastalir A, Bartók M (1996) J Catal 161:401
Dékány I, Turi L, Szücs A, Kiraly Z (1998) Colloids Surf A 141:405
Weickmann H, Tiller JC, Thomann R, Mülhaupt R (2005) Macromol Mater Eng 290:875
Divakar D, Manikandan D, Kalidoss G, Sivakumar T (2008) Catal Lett 125:277
Szöllösi G, Török B, Baranyi L, Bartók M (1998) J Catal 179:619
Balázsik K, Török B, Szakonyi G, Bartók M (1999) Appl Catal A 182:53
Török B, London G, Bartók M (2000) Synlett 631
Choudary BM, Madhi S, Chowdari NS, Kantam ML, Sreedhar B (2002) J Am Chem Soc 124:14127
Moreno-Mañas M, Pleixats R (2004) Fluorous nanoparticles. In: Gladysz JA, Curran DP, Horváth IT (eds) Handbook of fluorous chemistry. Wiley–VCH, Weinheim, p 491
Barthel-Rosa LP, Gladysz JA (1999) Coord Chem Rev 192:587
Horváth IT (1998) Acc Chem Res 31:641
Horváth IT, Rábai J (1994) Science 266:72
Djakovich L, Köhler K, de Vries JG (2007) The role of palladium nanoparticles as catalysts for carbon–carbon coupling reactions. In: Astruc D (ed). Wiley–VCH, Weinheim, p 303
Gaikwad AV, Holuigue A, Thathagar MB, ten Elshof JE, Rothenberg G (2007) Chem Eur J 13:6908
Reetz MT, de Vries JG (2004) Chem Commun 1559
Amman L (2003) Cation exchange and adsorption on clays and clay minerals. PhD thesis, Christian-Albrechts-Universität, Kiel, p 114
Meier LP, Kahr G (1999) Clays Clay Miner 47:386
Qin C, Lu W (2008) J Org Chem 73:7424
Hassan J, Hathroubi C, Gozzi C, Lemaire M (2001) Tetrahedron 57:7845
Mitsudome T et al (2007) Angew Chem Int Ed 46:3288
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The authors thank the Deutsche Forschungsgemeinschaft (DFG) for financial support within Sonderforschungsbereich SFB 428.
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Scheuermann, G.M., Thomann, R. & Mülhaupt, R. Catalysts Based Upon Organoclay with Tunable Polarity and Dispersion Behavior: New Catalysts for Hydrogenation, C–C Coupling Reactions and Fluorous Biphase Catalysis. Catal Lett 132, 355–362 (2009). https://doi.org/10.1007/s10562-009-0122-9
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DOI: https://doi.org/10.1007/s10562-009-0122-9