Abstract
A novel heterogeneous catalyst was prepared by immobilizing bifunctional acidic ionic liquid of metal Al substituted (BAIL-Al) onto the surface of magnetic γ-Al2O3, and characterized by FT-IR, TG, XRD, BET, XPS, VSM, SEM and TEM. The catalytic activity of the prepared solid catalyst was investigated for the conversion of xylose to furfural. On the basis, the effects of temperature, time, amount of catalyst and solvent were studied on the yield of furfural. A furfural yield of 67.5% with 97.3% xylose conversion was obtained from xylose using Fe3O4@Al2O3-(BAIL-Al) as the catalyst in DMSO at 140 °C for 3 h. The immobilized catalyst has the features of easily separation and recycling as well as good thermal stability. Thus, the immobilized catalyst can be efficiently and easily recycled at least five times without apparent loss of activity in xylose conversion and furfural yield.
Graphical Abstract
A novel heterogeneous catalyst was prepared by immobilized bifunctional acidic ionic liquid (BAIL-Al) onto the surface of magnetic γ-Al2O3, possessing unique physicochemical properties and excellent catalytic activity for xylose transformation have been developed.
Similar content being viewed by others
References
Zhou P, Zhang Z (2016) Catal Sci Technol 6(11):3694–3712
Liu B, Zhang Z (2016) ChemSusChem 9(16):2015–2036
Bozell JJ, Petersen GR (2010) ChemInform 12(28):539–554
Corma A, de la Torre O, Renz M, Villandier N (2011) Angew Chem Int Ed 50(10):2375–2378
Corma A, de la Torre O, Renz M (2011) ChemSusChem 4(11):1574–1577
Chheda JN, Románleshkov Y, Dumesic JA (2007) Green Chem 9(4):342–350
Dias AS, Lima S, Pillinger M, Valente AA (2006) Carbohydr Res 341(18):2946–2953
Jong WD, Marcotullio G (2010) Int J Chem React Eng 8(1):47–54
Morais ARC, Matuchaki MDDJ, Andreaus J, Bogel-Lukasik R (2016) Green Chem 18(10):2985–2994
Morais ARC, Bogellukasik R (2016) Green Chem 18(8):2331–2334
Peleteiro S, Santos V, Garrote G, Parajó JC (2016) Carbohydr Polym 146:20–25
Peleteiro S, Santos V, Parajó JC (2016) Carbohydr Polym 153:421–428
Peleteiro S, Lopes AMDC, Garrote G, Parajó JC, Bogel-Łukasik R (2015) Ind Eng Chem Res 54:8368–8373
Zhang Z, Zhao ZK (2010) Bioresour Technol 101(3):1111–1114
Liu B, Zhang Z, Zhao ZK (2013) Chem Eng J 215–216(3):517–521
Xiong Y, Zhang Z, Wang X, Liu B, Lin J (2014) Chem Eng J 235 (1):349–355
Matsagar BM, Munshi MK, Kelkar AA, Dhepe PL (2015) Catal Sci Technol 5(12):5086–5090
Peleteiro S, Rivas S, Alonso JL, Santos V, Parajó JC (2016) Bioresour Technol 202:181–191
Yang Y, Hu CW, Abu-Omar MM (2012) ChemSusChem 5(2):405–410
Zhang L, Yu H, Pan W, Dong H, Peng X (2012) Bioresour Technol 130C(2):110–116
Wu Z, Li Z, Wu G, Wang L, Lu S, Wang L, Wan H, Guan G (2014) Ind Eng Chem Res 53(8):3040–3046
Liu B, Zhang Z (2016) ACS Catal 6(1):326–338
Yin S, Sun J, Liu B, Zhang Z (2015) J Mater Chem A 3(9):4992–4999
Liu B, Ren Y, Zhang Z (2014) Green Chem 17 (3):1610–1617
Agirrezabal-Telleria I, García-Sancho C, Maireles-Torres P, Arias PL (2013) Chin J Catal 34(7):1402–1406
Weingarten R, Tompsett GA, Conner WC, Huber GW (2011) J Catal 279(279):174–182
Thyssen VV, Maia TA, Assaf EM (2015) J Braz Chem Soc 26 (1):22–31
Jenness GR, Christiansen MA, Caratzoulas S, Vlachos DG, Gorte RJ (2014) J Phys Chem C 118(24):12899–12907
Wang Y, Gu Z, Liu W, Yao Y, Wang H, Xia XF, Li W (2015) RSC Adv 5(75):60736–60744
Safaei S, Mohammadpoorbaltork I, Khosropour AR, Moghadam M, Tangestaninejad S, Mirkhani V (2013) Catal Sci Technol 3(10):2717–2722
Jing H, Wang X, Liu Y, Wang A (2015) Chin J Catal 36 (2):244–251
Taghavi M, Ghaemy M, Nasab SMA, Hassanzadeh M (2015) J Polym Res 22(2):1–12
Gu Z, Wang Y, Yao Y, Xia X, Wang H, Li W (2015) Catal Lett 145(12):2046–2054
Habibi N, Arandiyan H, Rezaei M (2016) RSC Adv 6(35):29576–29585
Zhang Q, Luo J, Wei Y (2011) ChemInform 42(14):2246–2254
Zheng J, Dong Y, Wang W, Ma Y, Hu J, Chen X, Chen X (2013) Nanoscale 5(11):4894–4901
Yaripour F, Shariatinia Z, Sahebdelfar S, Irandoukht A (2015) Fuel 139(139):40–50
Azgomi N, Mokhtary M (2015) J Mol Catal A 398 (4):58–64
Masouleh NSG, Taghizadeh M, Yaripour F (2014) Chem Eng Technol 37(9):1475–1482
Zhang Q, Su H, Luo J, Wei Y (2012) ChemInform 14(25):201–208
Peleteiro S, Lopes AMDC, Garrote G, Bogel-Łukasik R, Parajó JC (2015) Ind Crops Prod 77:163–166
Hu X, Westerhof R, Dong D, Wu L, Li CZ (2014) ACS Sustain Chem Eng 2(11):2562–2575
Rong C, Ding X, Zhu Y, Li Y, Wang L, Qu Y, Ma X, Wang Z (2012) Carbohydr Res 350(350):77–80
Iglesias J, Melero JA, Morales G, Paniagua M, Hernández B (2016) ChemCatChem 8(12):2089–2099
Huang R, Qi W, Su R, He Z (2010) ChemInform 46(24):1115–1117
Lima S, Neves P, Antunes MM, Pillinger M, Ignatyev N, Valente AA (2009) Appl Catal A 363(1–2):93–99
Zhang Z, Du B, Quan ZJ, Da YX, Wang XC (2014) Catal Sci Technol 4(3):633–638
Choudhary V, Sandler SI, Vlachos DG (2012) ACS Catal 2(9):2022–2028
Choudhary V, Caratzoulas S, Vlachos DG (2012) Carbohydr Res 368C(10):89–95
Danon B, Marcotullio G, Jong WD (2014) ChemInform 45(10):39–54
Author information
Authors and Affiliations
Corresponding authors
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Wu, C., Yuan, W., Huang, Y. et al. Conversion of Xylose into Furfural Catalyzed by Bifunctional Acidic Ionic Liquid Immobilized on the Surface of Magnetic γ-Al2O3 . Catal Lett 147, 953–963 (2017). https://doi.org/10.1007/s10562-017-1982-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-017-1982-z