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Pd/Cu-Free Cobalt-Catalyzed Suzuki and Heck Using Green Bio-Magnetic Hybrid and DFT-Based Theoretical Study

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Abstract

Several highly efficient and magnetically recyclable cobalt catalytic systems were prepared using magnetic chitosan and some safe and available organic compounds (Co-ligand@MNPs/Ch). The structure of these nanocomposites was confirmed by various physicochemical techniques such as FT-IR, XRD, TGA, VSM, TEM, SEM, CHNS and ICP-OES. These nano composites exhibit remarkable catalytic efficiency for Suzuki and Heck cross-coupling reactions in mild and green reaction conditions. The facile accessibility of starting materials, possible performance in air and eco-friendly conditions are merits of our catalysts. In addition, to describe and go insight to role and effect of ligands present in these catalysts, electrostatic interactions, density functional theory (DFT) model in molecular method were employed.

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Authors and Affiliations

  1. Department of Chemistry, Isfahan University of Technology, 8415683111, Isfahan, Iran

    Abdol R. Hajipour, Zahra Khorsandi, Hamidreza Jouypazadeh, Bahareh Mohammadi & Hossein Farrokhpour

  2. Department of Neuroscience, Medical School, University of Wisconsin, 1300 University Avenue, Madison, WI, 53706-1532, USA

    Abdol R. Hajipour

  3. Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, Shahreza, Iran

    Mehnoosh Ahmadi

Authors
  1. Abdol R. Hajipour
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  2. Zahra Khorsandi
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  3. Mehnoosh Ahmadi
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  4. Hamidreza Jouypazadeh
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  5. Bahareh Mohammadi
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  6. Hossein Farrokhpour
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Correspondence to Abdol R. Hajipour, Zahra Khorsandi or Hossein Farrokhpour.

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Hajipour, A.R., Khorsandi, Z., Ahmadi, M. et al. Pd/Cu-Free Cobalt-Catalyzed Suzuki and Heck Using Green Bio-Magnetic Hybrid and DFT-Based Theoretical Study. Catal Lett 151, 2842–2850 (2021). https://doi.org/10.1007/s10562-020-03487-3

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  • DOI: https://doi.org/10.1007/s10562-020-03487-3

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