Abstract
The life of transformer oil-paper insulation is determined by the insulation property of transformer cellulosic insulation. Existing studies have shown that sulfur corrosion poses a serious threat to the properties of transformer oil-immersed cellulosic insulation due to the reaction of corrosive sulfur dissolved in oil with copper winding. This paper investigated the effect of sulfur corrosion on the characteristics of transformer cellulosic insulation, cellulosic insulation winding samples with different degrees of sulfur corrosion were obtained through an accelerated thermal aging experiment. Then, short-/long-term withstand voltage tests for the cellulosic insulation winding were conducted. Experimental results showed that the contamination of sulfur corrosion had a minimal effect on the power–frequency breakdown voltage of the cellulosic insulation winding but considerably decreased its long-term electrical life. Combined with the analysis of the electrical/physical and chemical parameters of oil-immersed cellulosic insulation, the failure mechanism of transformer oil-immersed cellulosic insulation induced by sulfur corrosion was synthetically discussed and analyzed.
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References
IEC 60076-7 (2005) Power transformers—part 7: loading guide for oil-Immersed power transformers
IEC 60243-1 (2013) Electric strength of insulating materials—test methods—part 1: tests at power frequencies
Amimoto T, Hosokawa N, Nagao E, Tanimura J, Toyama S (2009) Concentration dependence of corrosive sulfur on copper-sulfide deposition on insulating paper used for power transformer insulation. IEEE Trans Dielectr Electr Insul 16(5):1489–1495
ANSI/IEEE Std 930 (1987) IEEE guide for the statistical analysis of electrical insulation voltage endurance data
Arroyo OH, Fofana I, Jalbert J, Ryadi M (2015) Relationships between methanol marker and mechanical performance of electrical insulation papers for power transformers under accelerated thermal aging. IEEE Trans Dielectr Electr Insul 22(6):3625–3632
Arroyo OH, Jalbert J, Fofana I, Ryadi M (2017) Temperature dependence of methanol and the tensile strength of insulation paper: kinetics of the changes of mechanical properties during ageing. Cellulose 24(2):1031–1039
Atejkova M, Kastanek F, Maleterova Y, Kuzilek V (2017) Removal of corrosive sulfur from insulating oils by natural sorbent and liquid-liquid extraction. IEEE Trans Dielectr Electr Insul 24:2383–2389
Bartnikas R, Srivastava K (2003) Power and communication cables: theory and applications. power and communication cables: theory and applications. IEEE Press, New York
Dahlund M (2009) Copper sulphide in transformer insulation. CIGRE WG A2-32, Final Report No. 378
Doble FC (1941) The A-C dielectric-loss and power-factor method for field investigation of electrical insulation. Trans Am Inst Electr Eng 60:934–939
Faheem AK, Asma T (2015) Effect of DBDS and DBPC on paper oil insulation of power transformers. IOSR J Electr Electron Eng 5:2015
Flora SD, Kumari MK, Rajan JS (2014) Study of modification of electric field distribution in paper-oil insulation of transformer in the presence of copper sulphide. In: IEEE international conference on dielectric liquids, pp 1–4
Gao S, Yang L (2019) Effects of sulfur corrosion on the properties of oil-paper insulation induced by dibenzyl disulfide. IEEE Trans Dielectr Electr Insul 16:1089–1097
Gao S, Yang L, Ding D (2018) Corrosion mechanism for copper sulfide formation induced by dibenzyl disulfide in oil-immersed insulation. IEEE Access 7:23100–23108
IEC 60296 (2012) Fluids for electrotechnical applications—unused mineral insulating oils for transformer and switchgear
IEEE 930-2004 (2004) IEEE guide for the statistical analysis of electrical insulation breakdown data
Jalbert J, Celis ER, Duchesne S, Morin B et al (2015) Kinetics of the production of chain-end groups and methanol from the depolymerization of cellulose during the ageing of paper/oil systems. Part 3: extension of the study under temperature conditions over 120 °C. Cellulose 22(1):829–848
Kato F, Amimoto T, Nagao E, Hosokawa N, Toyama S, Tanimura J (2011) Effect of DBDS concentration and heating duration on copper sulfide formation in oil-immersed transformer insulation. IEEE Trans Dielectr Electr Insul 18(6):1869–1876
Kawarai H, Fujita Y, Tanimura J, Toyama S, Yamada N, Nagao E, Amimoto T (2009) Role of dissolved copper and oxygen on copper sulfide generation in insulating oil. IEEE Trans Dielectr Electr Insul 16:2009
Khan FA, Rajan JS (2015) Experimental simulation of effects of copper sulphide on insulation system of transformers. IEEE Trans Dielectr Electr Insul 22:571–580
Lukic J (2015) Copper sulphide long term mitigation and risk assessment. CIGRE WG A2-40, Final Report No625
Maina R, Tumiatti V, Scatiggio F, Pompili M, Bartnikas R (2011) Transformers surveillance following corrosive sulfur remedial procedures. IEEE Trans Power Del 26:2391–2393
Malmedal K, Bates C, Cain D (2014) The measurement of soil thermal stability, thermal resistivity, and underground cable capacity. In: 2014 IEEE rural electric power conference
Rajan JS, Rudranna N (2013) Electric stress distribution in paper oil insulation due to sulphur corrosion of copper conductors. J Electrostat 71:429–434
Rajan JS, Flora SD, Ranganathaiah C (2016) Investigations of copper sulfide diffusion into paper insulation of transformers. IEEE Trans Dielectr Electr Insul 23:2421–2429
Rehman S, Alhems LM, Jadim R, AI-Faraj BA, AI-Mutairi KS, AI-Yemni AK (2017) Experimental investigation of temperature effect on corrosive sulfur formation in transformers. IEEE Trans Dielectr Electr Insul 24(5):3201–3206
Ren S, Zhong L, Yu X, Cao X (2010) Influence of copper sulfide on the electric field distribution and breakdown characteristics of oil-paper composite insulation. High Volt Eng 36(10):2444–2449 (in Chinese)
Ren S, Zhong L, Yu Q, Cao X, Li S (2012) Influence of the atmosphere on the reaction of dibenzyl disulfide with copper in mineral insulation oil. IEEE Trans Dielectr Electr Insul 19(3):849–854
Saha TK (2003) Review of modern diagnostic techniques for assessing insulation condition in aged transformers. IEEE Trans Dielectr Electr Insul 10:903–917
Sarathi R, Yadav KS, Swarna M (2015) Understanding the surface discharge characteristics of thermally aged copper sulphide diffused oil impregnated pressboard material. IEEE Trans Dielectr Electr Insul 22:2513–2521
Scatiggio F, Tumiatti V, Maina R (2009) Corrosive sulfur induced failures in oil-filled electrical power transformers and shunt reactors. IEEE Trans Power Del 24:1240–1248
Toyama S, Tanimura J, Yamada N, Nagao E, Amimoto T (2009) Highly sensitive detection method of dibenzyl disulfide and the elucidation of the mechanism. IEEE Trans Dielectr Electr Insul 16:509–515
Wang Y, Luo Y, Wang Y, Fei R (2019) Partial discharge damage mechanisms in laminated oil-paper insulation. Cellulose 26(9):1–12
Yang L, Gao S, Deng B, Zhang J, Sun W, Hu E (2016) Inhibition method for the degradation of oil-paper insulation and corrosive sulphur in a transformer using adsorption treatment. IET Gener Transm Dis 10:1893–1900
Zhou J, Yuan Y, Liu G, Zhang C (2019) The effects of corrosive sulfur in bushing: corrosion of aluminum foil and its effect of oil-paper insulation. IEEE Access 7:143735–143741
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Funding was provided by National Natural Science Foundation of China (Grant No. 51907014) and Natural Science Foundation of Chongqing Province of China (Grant No. cstc2019jcyj-msxmX0070).
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Gao, S., Yang, L. & Ke, T. Failure mechanism of transformer oil-immersed cellulosic insulation induced by sulfur corrosion. Cellulose 27, 7157–7174 (2020). https://doi.org/10.1007/s10570-020-03271-x
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DOI: https://doi.org/10.1007/s10570-020-03271-x