Abstract
Trihalomethanes (THMs) the by-products of chlorination in water treatment are recognised as a threat to public health due to their carcinogenicity. The photodegradation of THMs using hydrogen peroxide has been found to give increased removal efficiency and the outcome of the study may find, its application in designing a unit process for water treatment. Batch experiments were carried out using UV lamp of 83 W and 40% w/w Hydrogen peroxide (H2O2) in test waters between 2.5–10 pH range of chloroform, bromodichloromethane, dibromochloromethane and bromoform at 50–200 μg L−1 initial concentration. 92–100% removal of chloroform, bromodichloromethane, dibromochloromethane and bromoform were found with 0.1% of H2O2 and 90 min of UV exposure.
Similar content being viewed by others
References
Beltran, F. J., Gonalez, M., Rivas, J. and Acedo, B.: 1999, ‘Aqueous degradation of VOCs in the ozone combined with H2O2 or UV radiation process’, J. Env. Sci. Health A 34(3), 649–671.
Clarke, N. and Knowles, G.: 1992, ‘High purity water using H2O2 and Uv radiation’, Effluent Water Treat. J. 32(7), 335–341.
Glaze, W. H. and Lin, C. C.: 1984, Optimization of Liquid–liquid Extraction Methods for Analysis of Organics in Water, EPA-600/S4-83-052, USEPA.
Kormann, C., Bahemann, D. W. and Hoffmann, M. R.: 1991, ‘Photolysis of chloroform and other organic molecules in aqueous TiO2 suspensions’, Env. Sci. Technol. 25(3), 494–500.
Li, J. W. and Zu, Z.: 1996, ‘Effect of ultra-violet irradiation on the characteristics and THMs formation potential of humic acid’, Water Res. 30(2), 347–350.
Malaiyandi, M. and Husain Sadar, M.: 1980, ‘Pauline Lee; Ron O'Grady. Removal of organics in water using H2O2 in the presence of ultraviolet light’, Wat. Res. 14(8), 1131–1135.
Vogel, A. I.: 1959, Volumetric analysis. Quantitative Inorganic Analysis Theory and Practice, 2nd ed., Longman's Green and Co., London, p. 283.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rudra, A., Thacker, N.P. & Pande, S.P. Hydrogen Peroxide and Ultraviolet Irradiations in Water Treatment. Environ Monit Assess 109, 189–197 (2005). https://doi.org/10.1007/s10661-005-6372-0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10661-005-6372-0