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Study of lithiated Nafion ionomer for lithium batteries

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Abstract

Lithiated Nafion 112 ionomer was characterized by FT-IR spectroscopy, AC impedance, and cyclic voltammetry. The ionomer swollen with mixed solvents of propylene carbonate (PC) and ethylene carbonate shows ionic conductivity of 8.18×10−5Scm−1 at 25°C and good electrochemical stability to allow operation in Li/ionomer/LiCoO2 cells. The discharge capacity of the first cycle is 126mAhg−1. Significant capacity loss occurs during cycling due to the presence of PC. AC impedance shows that the passive layer formed at the Li/ionomer interface dominates the cycling performance of the cell.

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Authors and Affiliations

  1. Department of Chemistry, Tsinghua University, Beijing, 100084, China

    H. Y. Liang, X. P. Qiu, W. T. Zhu & L. Q. Chen

  2. Department of material science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing, 100083, China

    S. C. Zhang

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  1. H. Y. Liang
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  2. X. P. Qiu
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  3. S. C. Zhang
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  4. W. T. Zhu
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  5. L. Q. Chen
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Liang, H.Y., Qiu, X.P., Zhang, S.C. et al. Study of lithiated Nafion ionomer for lithium batteries. Journal of Applied Electrochemistry 34, 1211–1214 (2004). https://doi.org/10.1007/s10800-004-1767-0

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