Abstract
The two silver vanadium oxide phases—Ag2V4O11 and Ag4V2O6F2—were prepared by hydrothermal synthesis. The electrical conductivity of both silver vanadate powders was determined by the powder-solution-composite (PSC) method. The conductivities obtained were 0.0085 ± 0.0005 and 0.0005 ± 0.00015 S/cm for the Ag2V4O11 and Ag4V2O6F2, respectively, the first such report for the Ag4V2O6F2 phase. The optical gap and the transmission where studied by diffuse reflectance. Both were larger for Ag4V2O6F2 than Ag2V4O11, concomitant with a decrease in carrier content.
Similar content being viewed by others
References
J.-M. Tarascon, M. Armand, Nature 414, 359 (2001)
C.L. Schmidt, P.M. Skarstad, J. Power Sources 97–98, 742 (2001)
J. Drews, G. Fehrmann, R. Staub, R. Wolf, J. Power Sources 97–98, 747 (2001)
C. Schmidt, G. Tam, E. Scott, J. Norton, K. Chen, J. Power Sources 119–121, 979 (2003)
K.J. Takeuchi, A.C. Marschilok, S.M. Davis, R.A. Leising, E.S. Takeuchi, Coord. Chem. Rev. 219–221, 283 (2001)
E.M. Sorensen, H.K. Izumi, J.T. Vaughey, C.L. Stern, K.R. Poeppelmeier, J. Am. Chem. Soc. 127, 6347 (2005)
S.-Y. Chung, J.T. Bloking, Y.-M. Chiang, Nature 1, 123 (2002)
B.J. Ingram, T. Mason, J. Electrochem. Soc. 150, E396 (2003)
E.B. Segal, Chem. Heal. Saf. 7, 18 (2000)
D. Peters, R.J. Miethchen, Fluor. Chem. 79, 161 (1996)
J.C. Bertolini, J. Emerg. Med. 10, 163 (1992)
W.T.A. Harrison, T.M. Nenoff, T.E. Gier, G.D. Stucky, Inorg. Chem. 32, 2437 (1993)
B.A. Boukamp, Equivalent Circuit for Windows (University of Twente, The Netherlands, 2005)
L.Y. Woo, S. Wansom, T.O. Mason, J. Mater. Sci. 38, 2265 (2003)
M. Campo, L.Y. Woo, T.O. Mason, E.J. Garboczi, J. Electroceramics 9, 49 (2002)
R. Landauer, in Electrical Transport and Optical Properties of inhomogeneous media, ed. by J.C. Garland, D.B. Tanner, AIP Conf. Proc., vol 40 (American Institute of Physics, New York, 1978), p.2
R.E. Meredith, C.W. Tobias, in Advances in Electrochemistry and Electrochemical Engineering, vol. 2, ed. by C.W. Tobias (Interscience, New York, 1962), p. 15
J.F. Douglas, E.J. Garboczi, in Advances in Chemical Physics, vol. XCI, ed. by I. Prigogine, S. Rice (Wiley, New York, 1995), p. 85
E.J. Garboczi, J.F. Douglas, Phys. Rev. E 53, 6169 (1996)
D.S. McLachlan, J.-H. Hwang, T.O. Mason, J. Electroceramics 5, 37 (2000)
H. Fricke, J. Phys. Chem. 57, 934 (1953)
H. Fricke, Phys. Rev. 24, 575–587 (1924)
D. McLachlan, M. Blaszkiewicz, R. Newnhan, J. Am. Ceram. Soc. 73, 2187 (1990)
J. Newman, J. Electrochem. Soc. 113, 501 (1966)
B.J. Last, D.J. Thouless, Phys. Rev. Lett. 27, 1719 (1971)
S. Kirkpatrick, Rev. Mod. Phys. 45, 574 (1973)
D. Stauffer, Introduction to Percolation Theory (Taylor & Francis, London and Philadelphia, 1985)
M. Onoda, K. Kanbe, J. Phys., Condens. Matter 13, 6675 (2001)
J. Molenda, A. Stoklosa, T. Bak, Solid State Ionics 36, 53 (1989)
Y. Shimakawas, T. Numata, J. Tabuchi, J. Solid State Chem. 131, 138 (1997)
H. Kawaia, M. Nagatab, H. Kageyamac, H. Tukamoto, Electrochim. Acta 45, 315 (1999)
J. Molenda, Solid State Ionics 176, 1687 (2005)
C. Delacourt, L. Laffont, R. Bouchet, C. Wurm, J.-B. Leriche, M. Morcrette, J.-M. Tarascon, C. Masquelier, J. Electrochem. Soc. 152(5), A913–A921 (2005)
Acknowledgments
The authors gratefully acknowledge the support from the NSF-MRSEC program (grant no. DMR-0076097) at the Materials Research Center of Northwestern university.
We thank Dr. N. Erdman from Jeol Corp. and A. P. Merkle from Northwestern University for their help with the SEM images.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bertoni, M.I., Kidner, N.J., Mason, T.O. et al. Electrical and optical characterization of Ag2V4O11 and Ag4V2O6F2 . J Electroceram 18, 189–195 (2007). https://doi.org/10.1007/s10832-007-9025-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10832-007-9025-6