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Inclusion of molecular iodine into channels of the organic zeolite-like gossypol

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Abstract

Gossypol has been obtained in the zeolite-like form by desolvation of the 1:1 unstable solvate with dichloromethane. It demonstrates a high potential for an uptake of molecular iodine from the environment. In a case of single crystals a stable inclusion compound (gossypol)8·I2, preserving the crystal structure of the zeolite-like form, has been prepared. The iodine molecules occupy large cavities of the channels and are inclined as confirmed by the absence of a strong dichroism. The iodine molecules can be removed with the help of vacuum giving back to the zeolite-like form.

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Acknowledgements

Investigations have been carried out under the auspices of SCOPES (Switzerland) project 7UZPJ065576 between Uzbek and Swiss partners. We thank the EPSRC (UK) for provision of the diffractometer.

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Authors and Affiliations

  1. Institute of Bioorganic Chemistry, H. Abdullaev str. 83, Tashkent, 100125, Uzbekistan

    Samat A. Talipov, Bakhtiyar T. Ibragimov, Fatkhulla Kh. Tadjimukhamedov & Zavkibek G. Tiljakov

  2. Department of Chemistry and Biochemistry, University of Berne, Freiestrasse 3, Berne, 3012, Switzerland

    Tino Hertzsch & Jürg Hulliger

  3. School of Chemistry, The University of Nottingham, Nottingham, NG7 2RD, UK

    Alexander J. Blake

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  1. Samat A. Talipov
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  2. Bakhtiyar T. Ibragimov
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  3. Fatkhulla Kh. Tadjimukhamedov
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  4. Zavkibek G. Tiljakov
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  5. Alexander J. Blake
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  6. Tino Hertzsch
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  7. Jürg Hulliger
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Correspondence to Samat A. Talipov.

Additional information

Supplementary Data relating to this article are deposited with the Cambridge Crystallographic Data Centre as supplementary publication No. CCDC 226180.

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Talipov, S.A., Ibragimov, B.T., Tadjimukhamedov, F.K. et al. Inclusion of molecular iodine into channels of the organic zeolite-like gossypol. J Incl Phenom Macrocycl Chem 59, 287–292 (2007). https://doi.org/10.1007/s10847-007-9325-0

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  • DOI: https://doi.org/10.1007/s10847-007-9325-0

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