Abstract
The purpose of this work is surface characterization of GaAs solar cell using atomic force microscopy. The surface appearance influences the optical properties of the cells. It impacts light trapping and consequently affect the efficiency of the solar cells. In case of nano-structural surface, the properties are strongly depends on its geometrical characteristics. Surface appearance was studied by atomic force microscopy (AFM). Fractal analysis was done by the triangulation method and evaluation of statistical metrics was carrying out on the basis of AFM-data, before and after heating. The results of fractal analysis show the correlation of fractal dimension and statistical characteristics of surface topography. Characterization technique and data processing methodology are essential for description of the surface condition.
Similar content being viewed by others
References
L. Dejam, S.M. Elahi, H.H. Nazari, H. Elahi, S. Solaymani, A. Ghaderi, Structural and optical characterization of ZnO and AZO thin films: the influence of post-annealing. J. Mater. Sci.27, 685–696 (2016)
V. Dalouji, S. Elahi, Solaymani,, A. Ghaderi, H. Elahi, Carbon films embedded by nickel nanoparticles: fluctuation in hopping rate and variable-range hopping with respect to annealing temperature. Appl. Phys. A 122, 541 (2016)
V. Dalouji, S. Elahi, Solaymani,, A. Ghaderi, Absorption edge and the refractive index dispersion of carbon-nickel composite films at different annealing temperatures. Eur. Phys. J. Plus 131, 84 (2016)
S. Solaymani, A. Ghaderi, N.B. Nezafat, Comment on: characterization of microroughness parameters in titanium nitride thin films grown by dc magnetron sputtering. J. Fusion Energy 31, 591–591 (2012)
M. Molamohammadi, C. Luna, A. Arman, S. Solaymani, A. Boochani, A. Ahmadpourian, A. Shafiekhani, Preparation and magnetoresistance behavior of nickel nanoparticles embedded in hydrogenated carbon film. J Mater Sci 26, 6814–6818 (2015)
Roughness of solar cells. Available at: http://www.nanosurf.com/upload/appnote/100539_an00288_solar_cell_roughness.pdf. Accessed 31 Mar 2017
M. Topič, Sever M., B. LIPOVŠEK, A. ČAMPA, J. KRČ, Approaches and challenges in optical modelling and simulation of thin-film solar cells. Sol. Energy Mater. Sol. Cells 135, 57–66 (2015)
Ultrafast Laser Texturing for Enhanced Solar Cell Performance and Lower Cost. Available at: http://sionyx.com/pdf/solarcellperformancewhitepaper.pdf. Accessed 31 Mar 2017
Dmitruk NL, Borkovskaya OY, Dmitruk IN, Mamontova IB, Analysis of thin film surface barrier solar cells with a microrelief interface. Sol. Energy Mater. Sol. Cells 76, 625–635 (2003)
P. Škarvada, P. Tománek, P. Koktavý, R. Macků, J. Šicner, M. Vondra, D. Dallaeva, S. Smith, L. Grmela, A variety of microstructural defects in crystalline silicon solar cells. Appl. Surf. Sci. 312, 50–56 (2014)
A. Khanna, P.K. Basu, A. Filipovic, V. Shanmugam, C. Schmiga, A.G. Aberle, T. Mueller, Influence of random pyramid surface texture on silver screen-printed contact formation for monocrystalline silicon wafer solar cells. Sol. Energy Mater. Sol. Cells 132, 589–596 (2015)
Q. Jiang, J. Lu, J. Zhang, Y. Yuan, H. Cai, C. Wu, R. Sun, B. Lu, X. Pan, Z. Ye, Texture surfaces and etching mechanism of ZnO:Al films by a neutral agent for solar cells. Sol. Energy Mater. Sol. Cells 130, 264–271 (2014)
G. Yang, R.A. van Swaaij, H. Tan, O. Isabella, M. Zeman, Modulated surface textured glass as substrate for high efficiency microcrystalline silicon solar cells. Sol Energy Mater. Sol. Cells 133, 156–162 (2015)
B. Dou, R. Jia, H. Li, C. Chen, Y. Sun, Y. Zhang, W. Ding, Y. Meng, X. Liu, T. Ye, Fabrication of ultra-small texture arrays on multicrystalline silicon surface for solar cell application. Sol. Energy 91, 145–151 (2013)
X. Ren, W. Zi, Q. Ma, F. Xiao, F. Gao, S. Hu, Y. Zhou, S.F. Liu, Topology and texture controlled ZnO thin film electro deposition for superior solar cell efficiency. Sol. Energy Mater. Sol. Cells 134, 54–59 (2015)
L. Ding, L. Fanni, D. Messerschmidt, S. Zabihzadeh, M.M. Masis, S. Nicolay, C. Ballif, Tailoring the surface morphology of zinc oxide films for high-performance micromorph solar cells. Sol. Energy Mater. Sol. Cells 128, 378–385 (2014)
M. Erayerkan, V. Chawla, I. Repins, M.A. Scarpulla, Interplay between surface preparation and device performance in CZTSSe solar cells: effects of KCN and NH4OH etching. Sol. Energy Mater. Sol. Cells 136, 78–85 (2015)
H.B.T. Li, R.H. Franken , J.K. Rath, R.E. Schropp, Structural defects caused by a rough substrate and their influence on the performance of hydrogenated nano-crystalline silicon n–i–p solar cells. Sol. Energy Mater. Sol. Cells 93, 338–349 (2009)
M. Zeman, O. Isabella, S. Solntsev, K. Jäger, Modelling of thin-film silicon solar cells. Sol. Energy Mater. Sol. Cells 119, 94–111 (2013)
R.F. Múgica-Vidal, F. Alba-Elías, E. Sainz-García, J. Ordieres-Meré, Atmospheric plasma-polymerization of hydrophobic and wear-resistant coatings on glass substrates. Surf. Coat. Technol. 259, 374–385 (2014)
I. Roppolob, N. Shahzad, A. Sacco, E. Tresso, M. Sangermano, Multifunctional NIR-reflective and self-cleaning UV-cured coating for solar cell applications based on cycloaliphatic epoxy resin. Prog. Org. Coat 77, 458–462 (2014)
Ş. Ţălu, M. Bramowicz, S. Kulesza, S. Solaymani, A. Ghaderi, L. Dejam, A. Boochani, S.M. Elahi, Microstructure and micromorphology of ZnO thin films: case study on Al doping and annealing effects. Superlattices Microstruct. 93, 109–121 (2016). doi:10.1016/j.spmi.2016.03.003
Ş. Ţălu,, Micro and nanoscale characterization of three dimensional surfaces. Basics and Applications., ISBN 978-606-690-349-3 (Napoca Star Publishing House, Cluj-Napoca, 2015)
D. Dallaeva, Ş. Ţălu,, S. Stach, P. Škarvada, P. Tománek, L. Grmela, AFM imaging and fractal analysis of surface roughness of AlN epilayers on sapphire substrates. Appl. Surf. Sci. 312, 81–86 (2014). doi:10.1016/j.apsusc.2014.05.086
S. Stach, D. Dallaeva, Ş. Ţălu, P. Kaspar, P. Tománek, S. Giovanzana, L. Grmela, Morphological features in aluminum nitride epilayers prepared by magnetron sputtering. Mater. Sci-Pol. 33, 175–184 (2015). doi:10.1515/msp-2015-0036
S. Ramazanov, Ş. Ţălu,, D. Sobola, S. Stach, G. Ramazanov, Epitaxy of silicon carbide on silicon: micromorphological analysis of growth surface evolution. Superlattices Microstruct. 86, 395–402 (2015). doi:10.1016/j.spmi.2015.08.007
Ş. Ţălu, S. Stach, J. Zaharieva, M. Milanova, D. Todorovsky, S. Giovanzana, Surface roughness characterization of poly(methylmethacrylate) films with immobilized Eu(III) β-Diketonates by fractal analysis. Int. J. Polym. Anal. Charact. 19, 404–421 (2014). doi:10.1080/1023666X.2014.904149
Ş. Ţălu,, S. Stach, M. Ikram, D. Pathak, T. Wagner, J.-M. Nunzi, Surface roughness characterization of ZnO:TiO2—organic blended solar cells layers by atomic force microscopy and fractal analysis. Int. J. Nanosci. 13, 1450020–1450021 (2014). doi:10.1142/S0219581X14500203
Ş. Ţălu, A.J. Ghazai, S. Stach, A. Hassan, Z. Hassan, M. Ţălu, Characterization of surface roughness of Pt Schottky contacts on quaternary n-Al0.08In0.08Ga0.84N thin film assessed by atomic force microscopy and fractal analysis. J. Mater. Sci. 25, 466–477 (2014). doi:10.1007/s10854-013-1611-6
S. Stach, Ż. Garczyk,, Ş. Ţălu,, S. Solaymani, A. Ghaderi, R. Moradian, N.B. Nezafat, S.M. Elahi, H. Gholamali, Stereometric parameters of the Cu/Fe NPs thin films. J. Phys. Chem. C 119, 17887–17898 (2015). doi:10.1021/acs.jpcc.5b04676
Ş. Ţălu,, M. Bramowicz, S. Kulesza, A. Ghaderi, S. Solaymani, H. Savaloni, R. Babaei, Micromorphology analysis of specific 3-D surface texture of silver chiral nanoflower sculptured structures. J. Ind. Eng. Chem. 43, 164–169 (2016). doi:10.1016/j.jiec.2016.08.003
N. Naseri, S. Solaymani, A. Ghaderi, M. Bramowicz, S. Kulesza, Ş. Ţălu,, M. Pourreza, S. Ghasemi, Microstructure, morphology and electrochemical properties of Co nanoflake water oxidation electrocatalyst at micro-and nanoscale. RSC Adv. 7, 12923–12930 (2017). doi:10.1039/c6ra28795f
Ş. Ţălu,, M. Bramowicz, S. Kulesza, A. Ghaderi, V. Dalouji, S. Solaymani, M.F. Fathi Kenari, M. Ghoranneviss, Fractal features and surface micromorphology of diamond nanocrystals. J. Microsc. 264, 143–152 (2016). doi:10.1111/jmi.12422
Ş. Ţălu,, S. Solaymani, M. Bramowicz, S. Kulesza, A. Ghaderi, S. Shahpouri, S.M. Elahi, Effect of electric field direction and substrate roughness on three-dimensional self-assembly growth of copper oxide nanowires. J. Mater. Sci. 27, 9272–9277 (2016). doi:10.1007/s10854-016-4965-8
Ş. Ţălu,, S. Solaymani, M. Bramowicz, N. Naseri, S. Kulesza, A. Ghaderi, Surface micromorphology and fractal geometry of Co/CP/X (X = Cu, Ti, SM and Ni) nanoflake electrocatalysts. RSC Adv. 6, 27228–27234 (2016). doi:10.1039/C6RA01791F
A. Arman, T. Ghodselahi, M. Molamohammadi, S. Solayani, H. Zahrabi, A. Ahmadpourian, Phys. Chem. Surf. 51, 575–578 (2015)
N. Begum, A.S. Bhatti, F. Jabeen, S. Rubini, F. MARTELLI, in Phonon Confinement Effect in III-V Nanowires, ed. by P. Prete ed. (Intech, Rijeka, 2010)), p. 258
Gwyddion 2.37 software (Copyright © 2004–2007, 2009–2014 Petr Klapetek, David Nečas, Christopher Anderson). Available from: http://gwyddion.net. Accessed 10th June 2017
C. Douketis, Z. Wang, T.L. Haslett, M. Moskovits, Fractal character of cold-deposited silver films determined by low-temperature scanning tunneling microscopy. Phys. Rev. B 51, 11022–11032 (1995)
Ş. Ţălu, M. Bramowicz, S. Kulesza, S. Solaymani, A. Shafikhani, A. Ghaderi, M. Ahmadirad, Gold nanoparticles embedded in carbon film: micromorphology analysis. J. Ind. Eng. Chem. 35, 158–166 (2016). doi:10.1016/j.jiec.2015.12.029
Acknowledgements
Research described in the paper was financially supported by Internal Grant Agency of Brno University of Technology, grant No. FEKT-S-17-4626, by project Sensor, Information and Communication Systems SIX CZ.1.05/2.1.00/03.0072 and by the Grant Agency of the Czech Republic under no. GACR 15-05259S.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors claim to have no financial interest, either directly or indirectly, in the products or information listed in the article. The authors alone are responsible for the content and writing of the paper.
Appendix
Appendix
Statistical analysis was carried out with the software SPSS 14 for Windows (Chicago, IL, USA). One-way analysis of variance was applied for verification of results with Scheffé post-hoc tests. Statistically significant differences P are assumed to be 0.05 or less. The statistical parameters were expressed by Ra (average roughness), Rq (root-mean-square deviation), Ssk (skew), Sku (kurtosis), angles (θ, φ) (inclination).
In detail, these parameters have following meaning [38]:
-
RMS value of the height irregularities: this quantity is computed from data variance.
-
Ra value of the height irregularities: this quantity is similar to RMS value with the only difference in exponent (power) within the data variance sum. As for the RMS this exponent is q = 2, the Ra value is computed with exponent q = 1 and absolute values of the data (zero mean).
-
Height distribution skewness: computed from 3rd central moment of data values.
-
Height distribution kurtosis: computed from 4th central moment of data values.
-
Mean inclination of facets in area: computed by averaging normalized facet direction vectors.
-
Variation, which is calculated as the integral of the absolute value of the local gradient.
Rights and permissions
About this article
Cite this article
Ţălu, Ş., Nikola, P., Sobola, D. et al. Micromorphology investigation of GaAs solar cells: case study on statistical surface roughness parameters. J Mater Sci: Mater Electron 28, 15370–15379 (2017). https://doi.org/10.1007/s10854-017-7422-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-017-7422-4