Abstract
Acetic acid vapor thin film gas sensor was developed by synthesizing Mg-doped ZnO nanoparticles using a low cost and facile sol–gel route and were characterized using field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy and photoluminescence analysis. Morphological characterizations showed the formation of well-defined and highly crystalline ZnO nanoparticles on Si(100)/SiO2 substrate. Gas sensing characterization of dip coated Mg-doped ZnO thin films were performed in temperature range of 150–400 °C at different acetic acid vapor concentrations. At 300 °C, the sensitivity for pure ZnO, Zn0.98Mg0.02O and Zn0.94Mg0.06O samples at concentration of 200 ppm of acetic acid were 124, 78 and 67%, respectively. The highest sensitivity for Zn0.96Mg0.04O sample was 136% at the same vapor concentration and temperature. It showed a fast response time and recovery time (145 and 110 s, respectively).
Similar content being viewed by others
References
L. Wang, Y. Kang, X. Liu et al., ZnO nanorod gas sensor for ethanol detection. Sens. Actuators B 162, 237–243 (2012)
R. Kumar, O. Al-Dossary, G. Kumar, A. Umar, Zinc oxide nanostructures for NO2 gas–sensor applications: a review. Nano-Micro Lett. 7, 97–120 (2015). https://doi.org/10.1007/s40820-014-0023-3
R.K. Malik, R. Khanna, G.L. Sharma et al., Hydrogen sensing properties of copper-doped zinc oxide thin films. IEEE Sens. J. 15, 7021–7028 (2015)
B. Mandal, R. Singh, S. Mukherjee, Highly selective and sensitive methanol sensor using rose-like ZnO microcube and MoO3 micrograss based composite. IEEE Sens. J. 18, 2659–2666 (2018)
J. Chen, X. Pan, F. Boussaid et al., Breath level acetone discrimination through temperature modulation of a hierarchical ZnO gas sensor. IEEE Sens. Lett. 1, 1–4 (2017)
W. Wang, Y. Tian, X. Wang et al., Ethanol sensing properties of porous ZnO spheres via hydrothermal route. J. Mater. Sci. 48, 3232–3238 (2013)
J. Hu, F. Gao, S. Sang et al., Optimization of Pd content in ZnO microstructures for high-performance gas detection. J. Mater. Sci. 50, 1935–1942 (2015)
A. Hastir, R.L. Opila, N. Kohli et al., Deposition, characterization and gas sensors application of RF magnetron-sputtered terbium-doped ZnO films. J. Mater. Sci. 52, 8502–8517 (2017)
B. Yuliarto, M.F. Ramadhani, N.L.W. Septiani et al., Enhancement of SO2 gas sensing performance using ZnO nanorod thin films: the role of deposition time. J. Mater. Sci. 52, 4543–4554 (2017)
M.T. Hosseinnejad, M. Ghoranneviss, M.R. Hantehzadeh, E. Darabi, Growth, characterization, and investigation of H2 gas sensing performance of Al-doped ZnO thin films synthesized by plasma focus device. J. Mater. Sci. Mater. Electron. 27, 11308–11318 (2016)
M. Hjiri, N. Zahmouli, R. Dhahri et al., Doped-ZnO nanoparticles for selective gas sensors. J. Mater. Sci. Mater. Electron. 28, 9667–9674 (2017)
G. Eranna, Metal Oxide Nanostructures as Gas Sensing Devices (CRC Press, Boca Raton, 2011)
G. Neri, First fifty years of chemoresistive gas sensors. Chemosensors 3, 1–20 (2015)
Q. Jia, H. Ji, Y. Zhang et al., Rapid and selective detection of acetone using hierarchical ZnO gas sensor for hazardous odor markers application. J. Hazard. Mater. 276, 262–270 (2014)
X. Wang, F. Sun, Y. Duan et al., Highly sensitive, temperature-dependent gas sensor based on hierarchical ZnO nanorod arrays. J. Mater. Chem. C 3, 11397–11405 (2015)
M.-R. Yu, R.-J. Wu, M. Chavali, Effect of “Pt”loading in ZnO–CuO hetero-junction material sensing carbon monoxide at room temperature. Sens. Actuators B 153, 321–328 (2011)
P.P. Sahay, Zinc oxide thin film gas sensor for detection of acetone. J. Mater. Sci. 40, 4383–4385 (2005)
S. Christoulakis, M. Suchea, M. Katharakis et al., ZnO nanostructured transparent thin films by PLD. Rev. Adv. Mater. Sci. 10, 331–334 (2005)
M. Azuma, M. Ichimura, Fabrication of ZnO thin films by the photochemical deposition method. Mater. Res. Bull. 43, 3537–3542 (2008)
S.P. Wang, C.X. Shan, B. Yao et al., Electrical and optical properties of ZnO films grown by molecular beam epitaxy. Appl. Surf. Sci. 255, 4913–4915 (2009)
R. Yousefi, F. Jamali-Sheini, A.K. Zak, A comparative study of the properties of ZnO nano/microstructures grown using two types of thermal evaporation set-up conditions. Chem. Vap. Depos. 18, 215–220 (2012)
M. Dwivedi, J. Bhargava, A. Sharma et al., CO sensor using ZnO thin film derived by RF magnetron sputtering technique. IEEE Sens. J. 14, 1577–1582 (2014)
M. Kashif, Y. Al-Douri, U. Hashim et al., Characterisation, analysis and optical properties of nanostructure ZnO using the sol–gel method. Micro Nano Lett. 7, 163–167 (2012)
C. Jagadish, S.J. Pearton, Zinc Oxide Bulk, Thin Films and Nanostructures: Processing, Properties, and Applications (Elsevier, Oxford, 2011)
T.T. Trinh, N.H. Tu, H.H. Le et al., Improving the ethanol sensing of ZnO nano-particle thin films—the correlation between the grain size and the sensing mechanism. Sens. Actuators B 152, 73–81 (2011)
M.K. Chakravarthi, B. Bharath, DIP coated thick films of ZNO and its ethanol sensing properties, in 8th International Symposium on Mechatronics and its Applications (ISMA), pp 1–5, 2012
X.L. Cheng, H. Zhao, L.H. Huo et al., ZnO nanoparticulate thin film: preparation, characterization and gas-sensing property. Sens. Actuators B 102, 248–252 (2004)
R.S. Ganesh, E. Durgadevi, M. Navaneethan et al., Low temperature ammonia gas sensor based on Mn-doped ZnO nanoparticle decorated microspheres. J. Alloys Compd. 721, 182–190 (2017)
R. Zhang, W. Pang, Z. Feng et al., Enabling selectivity and fast recovery of ZnO nanowire gas sensors through resistive switching. Sens. Actuators B 238, 357–363 (2017)
D. Sett, D. Basak, Highly enhanced H2 gas sensing characteristics of Co: ZnO nanorods and its mechanism. Sens. Actuators B 243, 475–483 (2017)
F. Meng, N. Hou, Z. Jin et al., Sub-ppb detection of acetone using Au-modified flower-like hierarchical ZnO structures. Sens. Actuators B 219, 209–217 (2015)
F. Meng, H. Zheng, Y. Sun et al., UV-activated room temperature single-sheet ZnO gas sensor. Micro Nano Lett. 12, 813–817 (2017)
C.B. Jacobs, A.B. Maksov, E.S. Muckley et al., UV-activated ZnO films on a flexible substrate for room temperature O2 and H2O sensing. Sci. Rep. 7, 6053 (2017)
J. Gong, Y. Li, X. Chai et al., UV-light-activated ZnO fibers for organic gas sensing at room temperature. J. Phys. Chem. C 114, 1293–1298 (2009)
E. Espid, F. Taghipour, UV-LED photo-activated chemical gas sensors: a review. Crit. Rev. Solid State Mater. Sci. 42, 416–432 (2017)
M. Hjiri, R. Dhahri, K. Omri et al., Effect of indium doping on ZnO based-gas sensor for CO. Mater. Sci. Semicond. Process. 27, 319–325 (2014). https://doi.org/10.1016/j.mssp.2014.07.009
L. Giancaterini, C. Cantalini, M. Cittadini et al., Au and Pt nanoparticles effects on the optical and electrical gas sensing properties of sol–gel-based ZnO thin-film sensors. IEEE Sens. J. 15, 1068–1076 (2015)
S.M. Hosseini, I.A. Sarsari, P. Kameli, H. Salamati, Effect of Ag doping on structural, optical, and photocatalytic properties of ZnO nanoparticles. J. Alloys Compd. 640, 408–415 (2015)
N. Tamaekong, C. Liewhiran, A. Wisitsoraat, S. Phanichphant, Acetylene sensor based on Pt/ZnO thick films as prepared by flame spray pyrolysis. Sens. Actuators B 152, 155–161 (2011)
S. Wei, Y. Yu, M. Zhou, CO gas sensing of Pd-doped ZnO nanofibers synthesized by electrospinning method. Mater. Lett. 64, 2284–2286 (2010)
C. Dong, X. Liu, B. Han et al., Nonaqueous synthesis of Ag-functionalized In2O3/ZnO nanocomposites for highly sensitive formaldehyde sensor. Sens. Actuators B 224, 193–200 (2016)
J. Guo, J. Zhang, M. Zhu et al., High-performance gas sensor based on ZnO nanowires functionalized by Au nanoparticles. Sens. Actuators B 199, 339–345 (2014)
F. Meng, H. Zheng, Y. Sun et al., Trimethylamine sensors based on Au-modified hierarchical porous single-crystalline ZnO nanosheets. Sensors 17, 1478 (2017)
F. Meng, N. Hou, Z. Jin et al., Ag-decorated ultra-thin porous single-crystalline ZnO nanosheets prepared by sunlight induced solvent reduction and their highly sensitive detection of ethanol. Sens. Actuators B 209, 975–982 (2015). https://doi.org/10.1016/j.snb.2014.12.078
Q. Deng, S. Gao, T. Lei et al., Temperature & light modulation to enhance the selectivity of Pt-modified zinc oxide gas sensor. Sens. Actuators B 247, 903–915 (2017)
H. Gong, J.Q. Hu, J.H. Wang et al., Nano-crystalline Cu-doped ZnO thin film gas sensor for CO. Sens. Actuators B 115, 247–251 (2006)
A.J. Chen, X.M. Wu, Z.D. Sha et al., Structure and photoluminescence properties of Fe-doped ZnO thin films. J. Phys. D 39, 4762 (2006)
S.-Y. Kuo, W.-C. Chen, F.-I. Lai et al., Effects of doping concentration and annealing temperature on properties of highly-oriented Al-doped ZnO films. J. Cryst. Growth 287, 78–84 (2006)
R.F. Dezfuly, R. Yousefi, F. Jamali-Sheini, Photocurrent applications of Zn(1−x)CdxO/rGO nanocomposites. Ceram. Int. 42, 7455–7461 (2016)
C.H. Kwak, H.S. Woo, F. Abdel-Hady et al., Vapor-phase growth of urchin-like Mg-doped ZnO nanowire networks and their application to highly sensitive and selective detection of ethanol. Sens. Actuators B 223, 527–534 (2016). https://doi.org/10.1016/j.snb.2015.09.120
J. Xu, J. Han, Y. Zhang et al., Studies on alcohol sensing mechanism of ZnO based gas sensors. Sens. Actuators B 132, 334–339 (2008). https://doi.org/10.1016/j.snb.2008.01.062
C. Jin, S. Park, H. Kim et al., CO gas-sensor based on Pt-functionalized Mg-doped ZnO nanowires. Bull. Korean Chem. Soc. 33, 1993–1997 (2012)
A.J. Kulandaisamy, J.R. Reddy, P. Srinivasan et al., Room temperature ammonia sensing properties of ZnO thin films grown by spray pyrolysis: effect of Mg doping. J. Alloys Compd. 688, 422–429 (2016). https://doi.org/10.1016/j.jallcom.2016.07.050
W. Chebil, M.A. Boukadhaba, I. Madhi et al., Structural, optical and NO2 gas sensing properties of ZnMgO thin films prepared by the sol gel method. Phys. B 505, 9–16 (2017). https://doi.org/10.1016/j.physb.2016.10.028
K. Karthick, D. Srinivasan, J.B. Christopher, Fabrication of highly c-axis Mg doped ZnO on c-cut sapphire substrate by rf sputtering for hydrogen sensing. J. Mater. Sci. Mater. Electron. 28, 11979–11986 (2017)
K. Vijayalakshmi, K. Karthick, Growth of highly c-axis oriented Mg:ZnO nanorods on Al2O3 substrate towards high-performance H2 sensing. Int. J. Hydrogen Energy 39, 7165–7172 (2014). https://doi.org/10.1016/j.ijhydene.2014.02.123
Y. Liu, T. Hang, Y. Xie et al., Effect of Mg doping on the hydrogen-sensing characteristics of ZnO thin films. Sens. Actuators B 160, 266–270 (2011). https://doi.org/10.1016/j.snb.2011.07.046
A. Kharatzadeh, F. Jamali-Sheini, R. Yousefi, Excellent photocatalytic performance of Zn(1−x)MgxO/rGO nanocomposites under natural sunlight irradiation and their photovoltaic and UV detector applications. Mater. Des. 107, 47–55 (2016)
J. Zhang, F. Liao, Y. Zhu et al., Visible-light-enhanced gas sensing of CdSxSe1−x nanoribbons for acetic acid at room temperature. Sens. Actuators B 215, 497–503 (2015)
C. Wang, S. Ma, A. Sun et al., Characterization of electrospun Pr-doped ZnO nanostructure for acetic acid sensor. Sens. Actuators B 193, 326–333 (2014)
X.B. Li, Q.Q. Zhang, S.Y. Ma et al., Microstructure optimization and gas sensing improvement of ZnO spherical structure through yttrium doping. Sens. Actuators B 195, 526–533 (2014)
Z. Jiao, M. Wu, Z. Qin et al., Nano zinc ferrite acetic acid gas sensor for smuggled drug detection in southern China. Sens. Transducers Mag. 37, 24–29 (2003)
N. Al-Hardan, M.J. Abdullah, A.A. Aziz, H. Ahmad, ZnO gas sensor for testing vinegar acid concentrations. Sains Malays. 40, 67–70 (2011)
A. Sinha, S. Chakrabarti, B. Chaudhuri et al., Oxidative degradation of strong acetic acid liquor in wastewater emanating from hazardous industries. Ind. Eng. Chem. Res. 46, 3101–3107 (2007)
R. Yousefi, J. Beheshtian, S.M. Seyed-Talebi et al., Experimental and theoretical study of enhanced photocatalytic activity of Mg-doped ZnO NPs and ZnO/rGO nanocomposites. Chem.-Asian J. 13, 194–203 (2018). https://doi.org/10.1002/asia.201701423
J.H. Li, Y.C. Liu, C.L. Shao et al., Effects of thermal annealing on the structural and optical properties of MgxZn1−xO nanocrystals. J. Colloid Interface Sci. 283, 513–517 (2005)
G. Ning, X. Zhao, J. Li, Structure and optical properties of MgxZn1−xO nanoparticles prepared by sol–gel method. Opt. Mater. 27, 1–5 (2004)
K. Vijayalakshmi, K. Karthick, Influence of annealing on the photoluminescence of nanocrystalline ZnO synthesized by microwave processing. Philos. Mag. Lett. 92, 710–717 (2012)
R. Dhahri, M. Hjiri, L. El Mir et al., CO sensing characteristics of In-doped ZnO semiconductor nanoparticles. J. Sci. Adv. Mater. Devices 2, 34–40 (2017)
A.S.M. Iftekhar Uddin, D.T. Phan, G.S. Chung, Low temperature acetylene gas sensor based on Ag nanoparticles-loaded ZnO-reduced graphene oxide hybrid. Sens. Actuators B 207, 362–369 (2015). https://doi.org/10.1016/j.snb.2014.10.091
M. Takata, D. Tsubone, H. Yanagida, Dependence of electrical conductivity of ZnO on degree of sintering. J. Am. Ceram. Soc. 59, 4–8 (1976)
A. Sáaedi, R. Yousefi, Improvement of gas-sensing performance of ZnO nanorods by group-I elements doping. J. Appl. Phys. 122, 224505 (2017)
S. Fujitsu, K. Koumoto, H. Yanagida et al., Change in the oxidation state of the adsorbed oxygen equilibrated at 25 C on ZnO surface during room temperature annealing after rapid quenching. Jpn. J. Appl. Phys. 38, 1534 (1999)
L. Schmidt-Mende, J.L. MacManus-Driscoll, ZnO–nanostructures, defects, and devices. Mater. Today 10, 40–48 (2007)
J. Xu, Q. Pan, Z. Tian, Grain size control and gas sensing properties of ZnO gas sensor. Sens. Actuators B 66, 277–279 (2000)
M.A. Carpenter, S. Mathur, A. Kolmakov, Metal Oxide Nanomaterials for Chemical Sensors (Springer, New York, 2012)
D. Mishra, A. Srivastava, A. Srivastava, R.K. Shukla, Bead structured nanocrystalline ZnO thin films: synthesis and LPG sensing properties. Appl. Surf. Sci. 255, 2947–2950 (2008)
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
There are no conflicts of interest to declare.
Rights and permissions
About this article
Cite this article
Khorramshahi, V., Karamdel, J. & Yousefi, R. Acetic acid sensing of Mg-doped ZnO thin films fabricated by the sol–gel method. J Mater Sci: Mater Electron 29, 14679–14688 (2018). https://doi.org/10.1007/s10854-018-9604-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-018-9604-0