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High energy storage efficiency and high electrostrictive coefficients in BNT–BS–xBT ferroelectric ceramics

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Abstract

(1 − x)[0.9(Bi0.5Na0.5)TiO3–0.1BiScO3]–xBaTiO3 (BNT–BS–xBT) ceramics are prepared by the traditional solid-state sintering. The structure, morphology, ferroelectricity, strain, energy storage, dielectricity, and impedance of the BNT–BS–xBT ceramics are investigated. XRD shows that all ceramics have pseudo-cubic structures. The results also show that BT can refine the grain size of the ceramics and reduce the corresponding density. At x = 0.20, the energy storage performance of the ceramics is optimum (Wrec = 0.563 J/cm3, η = 63%). At x = 0.10, the electrostriction coefficient (Q33) of the ceramics reaches 2.72325 × 10−2 m4/C2. Dielectric and impedance spectroscopies show that the ceramics are relaxor ferroelectrics and have good insulation properties.

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Acknowledgements

This work is supported by the National Nature Science Foundation of China (Grant Nos. 11664006, 61965007), Guangxi Nature Science Foundation (Grant No. 2018GXNSFDA281042), and Guangxi Key Laboratory of Information Materials (Grant No. 171009-Z).

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Correspondence to Hua Wang or Jiwen Xu.

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Sun, Y., Wang, H., Liu, G. et al. High energy storage efficiency and high electrostrictive coefficients in BNT–BS–xBT ferroelectric ceramics. J Mater Sci: Mater Electron 31, 5546–5553 (2020). https://doi.org/10.1007/s10854-020-03119-x

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