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Triethyl ammonium salt of O,O′-bis(p-tolyl)dithiophosphate, [Et3NH]+[(4-MeC6H4O)2PS2]−

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Triethyl ammonium Salt of O,O′-bis(p-tolyl)dithiophosphate and O,O′-bis(m-tolyl)dithiophosphate have been obtained by reaction of p- and m-cresol, respectively with P2S5 in toluene and have been characterized by elemental analysis, IR, 1H and 31P NMR spectroscopy. The molecular structure of O,O′-bis(p-tolyl)dithiophosphate has been determined. Crystal data: [Et3NH]+[(4-MeC6H4O)2PS2]−: Monoclinic, P21/c, a=15.2441(9) Å, b=10.415(2) Å, c=3.9726(9) Å, β=91.709(7)°, V=2217.5(1) Å−3, Z=4.

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Acknowledgment

M.N. thanks the CSIR, New Delhi for financial support. M.B.H. thanks the UK Engineering and Physical Sciences Council for support of the X-ray facilities at Southampton University. J.E.D. thanks the University of Windsor for financial support.

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Authors and Affiliations

  1. Department of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK

    A. L. Bingham, M. B. Hursthouse & M. E. Light

  2. Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, N9B 3P4, Canada

    J. E. Drake

  3. Department of Pure & Applied Chemistry, M.D.S. University, Ajmer, 305 009, India

    C. Gurnani, M. Nirwan & R. Ratnani

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  1. A. L. Bingham
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  2. J. E. Drake
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  3. C. Gurnani
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  4. M. B. Hursthouse
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  5. M. E. Light
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  6. M. Nirwan
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  7. R. Ratnani
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Corresponding author

Correspondence to R. Ratnani.

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Supplementary materials

Additional material available from the Cambridge Crystallographic Data Centre (CCDC no. 600927 for [Et3NH]+[(4-MeC6H4O)2PS2]− comprises the final atomic coordinates for all atoms, thermal parameters, and a complete listing of bond distances and angles. Copies of this information may be obtained free of charge on application to The Director, 12 Union Road, Cambridge CB2 2EZ, UK (fax: +44-1223-336033; email: deposit@ccdc.cam.ac.uk or www:http://www.ccdc.cam.ac.uk).

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Bingham, A.L., Drake, J.E., Gurnani, C. et al. Triethyl ammonium salt of O,O′-bis(p-tolyl)dithiophosphate, [Et3NH]+[(4-MeC6H4O)2PS2]− . J Chem Crystallogr 36, 627–630 (2006). https://doi.org/10.1007/s10870-006-9107-3

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  • DOI: https://doi.org/10.1007/s10870-006-9107-3

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