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Single crystals of calcium and strontium phenylphosphonate grown via hydrothermal crystallization

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Single crystals of Ca(HO3PC6H5)2 (1) and Sr(HO3PC6H5)2 (2) have been obtained via the crystallization of their respective amorphous powders. The amorphous compounds were synthesized by traditional solution routes and were subsequently crystallized at 160°C in a Teflon-lined autoclave containing 1–3 mL distilled water. The resultant single crystals were physically isolated and their structures determined by single crystal X-ray diffraction. The two compounds are isostructural and crystallize in space group C2/c with lattice parameters of a = 31.267(3) Å, b = 5.6185(6) Å, c = 7.7202(8) Å, β = 101.924(2)°; and a = 31.514(4) Å, b = 5.8098(8) Å, c = 7.8218(10) Å, β = 102.063(3)° for the calcium and strontium phenylphosphonate, respectively.

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Acknowledgement

Funding for this research was provided by the University of South Carolina NanoCenter.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter St., Columbia, SC, 29208, US

    John W. Stone, Mark D. Smith & Hans-Conrad zur Loye

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  1. John W. Stone
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  2. Mark D. Smith
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  3. Hans-Conrad zur Loye
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Correspondence to Hans-Conrad zur Loye.

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Supplementary Materials

CSD # 271466 and 144289 (compounds 1 and 2 respectively) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk/ conts/retrieving.html [or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, U.K.; fax: +44(0)1223-336033; e-mail: deposit@ccdc. cam.ac.uk].

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Stone, J.W., Smith, M.D. & Loye, HC.z. Single crystals of calcium and strontium phenylphosphonate grown via hydrothermal crystallization. J Chem Crystallogr 37, 103–108 (2007). https://doi.org/10.1007/s10870-006-9155-8

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  • DOI: https://doi.org/10.1007/s10870-006-9155-8

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