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Self-Assembled Superstructure of Xanthene Derivatives

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Abstract

Various multi carbon homologations of 9-phenyl-9H-xanthen-9-ol (1) were obtained through a C-C bond formation by reacting it with various enolisable ketones in the presence of 1,1′-(ethane-1,2-diyl)dipyridinium bistribromide (EDPBT). All the ten derivatives along with the starting xanthen-9-ol have been characterized by single crystal X-ray diffraction. They all form self-assembled superstructure in the solid state. The self-assembling patterns in these supramolecular architectures were explained based on steric and electronic nature of the pendant arm.

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Acknowledgement

GD wishes to thanks CSIR for grant (Grant no. 01(1948)/04/EMR-II). B. K. P and acknowledge the support of this research from DST (SR/S1/OC-15/2006) and CSIR (01/1946/04/EMR-II), New Delhi. S. M and V. K acknowledges the financial support to the institute. Thanks are due to CIF IIT Guwahati for NMR spectra, DST FIST for XRD facility.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, Guwahati, Assam, India

    Veerababurao Kavala, Siva Murru, Bhisma K. Patel & Gopal Das

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  1. Veerababurao Kavala
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  2. Siva Murru
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  3. Bhisma K. Patel
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  4. Gopal Das
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Corresponding author

Correspondence to Gopal Das.

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Kavala, V., Murru, S., Patel, B.K. et al. Self-Assembled Superstructure of Xanthene Derivatives. J Chem Crystallogr 37, 527–535 (2007). https://doi.org/10.1007/s10870-007-9201-1

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  • DOI: https://doi.org/10.1007/s10870-007-9201-1

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