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Room Temperature Syntheses, Structures and Magnetic Properties of Two Heterometallic Tetranuclear Clusters

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Abstract

Two new heterometallic tetranuclear clusters [M2Na2(hmb)4(N3)2(CH3CN)2]·(CH3CN)2 (M = Ni (1), M = Co (2), Hhmb is 2-hydroxy-3-methoxy-benzaldehyde) have been synthesized at room temperature and structurally characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. Intracluster, compounds 1 and 2 display dominant ferromagnetic interaction through double μ 1,1,1-N3 bridges, while intercluster, 1 and 2 display weak anti-ferromagnetic interaction and ferromagnetic interaction, respectively.

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Acknowledgments

This work is financially supported by the National Nature Science Foundation of China (No. 21161006), and Program for Excellent Talents in Guangxi Higher Education Institutions (Gui Jiao Ren [2012]41).

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Authors and Affiliations

  1. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Ru-Xia Zhao, Hong Hai, Gui Li, Hai-Yang Zhang, Qiu-Ping Huang, Shu-Hua Zhang & He-Ping Li

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  1. Ru-Xia Zhao
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Correspondence to Hong Hai, Shu-Hua Zhang or He-Ping Li.

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Zhao, RX., Hai, H., Li, G. et al. Room Temperature Syntheses, Structures and Magnetic Properties of Two Heterometallic Tetranuclear Clusters. J Clust Sci 25, 1541–1552 (2014). https://doi.org/10.1007/s10876-014-0750-0

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