Skip to main content
SpringerLink
Log in

Two New Borates Containing [B5O6(OH)4] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH3COO− Group

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

Two new borate clusters, [C4H11N2O][C4H9N2][B5O6(OH)4]2 (1), [Cd(dien)2][B5O6(OH)4]2 (2, dien = diethylenetriamine), have been obtained under solvothermal conditions and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray structural analysis, respectively. Crystal data for 1: monoclinic, P21/c, a = 18.6975(5) Å, b = 15.3413(8) Å, c = 9.6691(3) Å, β = 90.462(3)°, Z = 4. Crystal data for 2: triclinic, P-1, a = 8.6107(4) Å, b = 9.3504(4) Å, c = 18.9631(4) Å, α = 103.798(4), β = 91.940(4)°, γ = 94.134(4)°, Z = 2. They all consist of [B5O6(OH)4]− clusters and further extend to 3-D frameworks via extensive hydrogen-bonding interactions. Interestingly, a novel in situ organic reaction between ethylenediamine and CH3COO− group has been observed during the formation of compound 1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. C. L. Christ and J. R. Clark (1977). Phys. Chem. Miner. 2, 59.

    Article  CAS  Google Scholar 

  2. G. Heller (1986). Top. Curr. Chem. 131, 39.

    Article  CAS  Google Scholar 

  3. P. C. Burns, J. D. Grice, and F. C. Hawthorne (1995). Can. Mineral. 33, 1131.

    CAS  Google Scholar 

  4. C. Chen, Y. Wang, B. Wu, K. Wu, W. Zeng, and L. Yu (1995). Nature. 373, 322.

    Article  CAS  Google Scholar 

  5. P. C. Burns (1995). Can. Mineral. 33, 1167.

    CAS  Google Scholar 

  6. J. D. Grice, P. C. Burns, and F. C. Hawthorne (1999). Can. Mineral. 37, 731.

    CAS  Google Scholar 

  7. M. Touboul, N. Penin, and G. Nowogrocki (2003). Solid State Sci. 5, 1327.

    Article  CAS  Google Scholar 

  8. Z. T. Yu, Z. Shi, Y. S. Jiang, H. M. Yuan, and J. S. Chen (2002). Chem. Mater. 14, 1314.

    Article  CAS  Google Scholar 

  9. D. M. Schubert, F. Alam, M. Z. Visi, and C. B. Knobler (2003). Chem. Mater. 15, 866.

    Article  CAS  Google Scholar 

  10. J. L. Rowsell, C. N. J. Talor, and L. F. Nazar (2002). J. Am. Chem. Soc. 124, 6522.

    Article  CAS  Google Scholar 

  11. C. Chen, B. Wu, A. Jiang, and G. You (1985). Sci. Sin. Ser. B 28, 235.

    Google Scholar 

  12. C. Chen, Y. Wu, A. Jiang, B. Wu, G. You, R. Li, and S. Lin (1989). J. Opt. Soc. Am. B 6, 616.

    Article  CAS  Google Scholar 

  13. Y. Mori, I. Kuroda, S. Nakajima, T. Sasaki, and S. Nakai (1995). Appl. Phys. Lett. 67, 1818.

    Article  CAS  Google Scholar 

  14. Y. Wu, T. Sasaki, S. Nakai, A. Yokotani, H. Tang, and C. Chen (1993). Appl. Phys. Lett. 62, 2614.

    Article  CAS  Google Scholar 

  15. Z.-N. Lin and G.-Y. Yang (2011). Eur. J. Inorg. Chem. 26, 3857–3867.

    Article  Google Scholar 

  16. G. M. Sheldrick, SHELXS-2013, Program for Solution of Crystal Structures (University of Göttingen, Göttingen, 2013).

  17. G. M. Sheldrick, SHELXS-2013, Program for Solution of Crystal Refinement (University of Göttingen, Göttingen, 2013).

  18. M. Touboul, E. Bertourn, and L. Seguin (1996). Mater. Sci. Forum. 228, 741–746.

    Article  Google Scholar 

  19. K. Timper, G. Heller, and M. Shakibaie-Moghadam (1990). Z. Naturforsch. B 45, 1155–1166.

    Article  CAS  Google Scholar 

  20. W. H. Zachariasen and H. A. Plettinger (1963). Acta Crystallogr. 16, 376–379.

    Article  CAS  Google Scholar 

  21. H. Behm (1984). Acta Crystallogr. C40, 1114–1116.

    CAS  Google Scholar 

  22. P. Becker, P. Held, and L. Bohaty (2000). Cryst. Res. Technol. 35, 1251–1262.

    Article  CAS  Google Scholar 

  23. S. Menchetti and C. Sabelli (1978). Acta Crystallogr. B34, 45–49.

    Article  CAS  Google Scholar 

  24. H. Xing, J. Li, and W. Yan (2008). Chem Mater. 20, 4179–4181.

    Article  CAS  Google Scholar 

  25. M. Castro, R. Garcia, and S. J. Warrender (2007). Chem Commun. 33, 3470–3472.

    Article  Google Scholar 

  26. G. J. Cao, J. Lin, and W. H. Fang (2011). Dalton Trans. 40, 2940–2946.

    Article  CAS  Google Scholar 

  27. D. M. Schubert, M. Z. Visi, and C. B. Knobler (2000). Inorg. Chem. 39, 2250.

    Article  CAS  Google Scholar 

  28. M. Z. Visi, C. B. Knobler, J. J. Owen, M. I. Khan, and D. M. Schubert (2006). Cryst. Growth Des. 6, 538.

    Article  CAS  Google Scholar 

  29. G. Z. Liu, L. Y. Xin, and L. Y. Wang (2011). Inorg. Chem. Commun. 14, 775.

    Article  CAS  Google Scholar 

  30. C. E. Weir (1966). J. Res. Nafl. Bur. Stand. Sect. A70, 153.

    Article  Google Scholar 

  31. C. E. Weir and R. Schroeder (1964). J. Res. Nafl. Bur. Stand. Sect. A68, 465.

    Article  Google Scholar 

  32. J. Krogh-Moe (1965). Phys. Chem. Glasses. 6, 46.

    CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the NSFC (Nos. 91122028, 21221001, 50872133), the NSFC for Distinguished Young Scholars (No. 20725101), and the 973 program (Nos. 2014CB932101 and 2011CB932504).

Author information

Authors and Affiliations

  1. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China

    Yuan Liu, Huan He, Bai-Feng Yang, Qiang Zhang & Guo-Yu Yang

Authors
  1. Yuan Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Huan He
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Bai-Feng Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Qiang Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Guo-Yu Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Qiang Zhang or Guo-Yu Yang.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 224 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, Y., He, H., Yang, BF. et al. Two New Borates Containing [B5O6(OH)4] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH3COO− Group. J Clust Sci 26, 1537–1545 (2015). https://doi.org/10.1007/s10876-015-0845-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-015-0845-2

Keywords

Search

Navigation