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Thermo-responsive Ruthenium Dendrimer-based Catalysts for Hydrogenation of the Aromatic Compounds and Phenols

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Abstract

In this work thermo-responsive ruthenium catalysts, based on the poly(propylene imine) dendrimers cross-linked with the poly(ethylene glycol) diglycidyl ether, have been prepared for the first time. The materials obtained were characterized by X-ray photoelectron spectroscopy and transmission electron microscopy, and tested in the phenol and benzene hydrogenation. Conditions for the metal impregnation into the polymeric matrix were demonstrated to have a great influence both on physical chemical properties of the synthesized catalysts (metal loading, mean particles size, surface structure etc.), and, as a consequence, on their hydrogenation activity and thermo-responsive properties.

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Acknowledgments

This work was supported by the Russian Foundation for Basic Research, project No. 16-33-60101. Also, we thank Elena Skryleva (National University of Science and Technology “MISIS”, Moscow, Russia) for XPS facilities.

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Authors and Affiliations

  1. Department of Petroleum Chemistry and Organic Catalysis, Moscow State University, Moscow, Russian Federation, 119991

    E. Karakhanov, A. Maximov, A. Zolotukhina, Yu. Kardasheva & M. Talanova

  2. A. V. Topchiev Institute of Petrochemical Synthesis RAS, Moscow, Russian Federation, 119991

    A. Maximov

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  1. E. Karakhanov
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Correspondence to E. Karakhanov.

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Karakhanov, E., Maximov, A., Zolotukhina, A. et al. Thermo-responsive Ruthenium Dendrimer-based Catalysts for Hydrogenation of the Aromatic Compounds and Phenols. J Inorg Organomet Polym 26, 1264–1279 (2016). https://doi.org/10.1007/s10904-016-0399-2

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