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Direct hydrothermal synthesis and characterization of framework-substituted Co(Mn)-Beta zeolites

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Abstract

Isomorphously substituted Co(Mn)-Beta zeolites were directly synthesized through a static hydrothermal approach. The silica-metal precursor was prepared by co-hydrolysis of tetraethylorthosilicate with cobalt or manganese nitrates in acidic media, which was adjusted to the strong basic condition by adding the structural directing agent (tetraethylammonium hydroxide) and Al source (sodium aluminate) for the subsequent hydrothermal crystallization. The products were characterized by X-ray diffraction, inductively coupling plasma elemental analysis, Brunauer–Emmett–Teller surface area, nitrogen sorption isotherm, FT-IR, UV–vis, and SEM. The results show that Co or Mn ions are incorporated into the framework of zeolite Beta, and the thus obtained Co(Mn)-Beta zeolites are nano-structured zeolite crystallites. The acidic co-hydrolysis/considention is proposed to facilitate the formation of metal-bearing nucleus for growing Co(Mn)-Beta crystals.

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Acknowledgments

The authors thank the National Natural Science Foundation of China (Grant nos. 20976084, 21136005 and 21101094), Jiangsu Provincial Natural Science Foundation (SBK201123111), and PAPD.

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Authors and Affiliations

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, No. 5 Xin Mofan Road, Nanjing, 210009, China

    Yue Yao, Fangfang Cao, Jing Gu, Yu Zhou & Jun Wang

  2. College of Sciences, Nanjing University of Technology, No. 5 Xin Mofan Road, Nanjing, 210009, China

    Yajing Wu

Authors
  1. Yue Yao
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  2. Fangfang Cao
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  3. Jing Gu
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  6. Jun Wang
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Correspondence to Jun Wang.

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Yao, Y., Cao, F., Gu, J. et al. Direct hydrothermal synthesis and characterization of framework-substituted Co(Mn)-Beta zeolites. J Porous Mater 20, 891–896 (2013). https://doi.org/10.1007/s10934-012-9666-y

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