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A facile preparation of palladium Schiff base complex supported into MCM-41 mesoporous and its catalytic application in Suzuki and Heck reactions

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Abstract

A simple and efficient method for phosphine-free C–C coupling reactions such as Heck and Suzuki reactions in the presence of pyrrole Schiff base complex of palladium immobilized on mesoporous mesoporous of MCM-41 (Pd-Py-MCM-41) has been reported. The Suzuki reaction was carried out in PEG-400 using phenylboronic acid (PhB(OH)2). Pd-Py-MCM-41 has been found as a promising catalyst for Heck reaction of butyl acrylate with aryl halides (including Cl, Br and I). The catalyst was characterized by FT-IR, TEM, XRD, SEM, BET and ICP-OES techniques. The protocol proves to be efficient and environmentally benign in terms of high yield, easy of recovery and reusability of catalyst.

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Acknowledgments

This work was supported by the research facilities of Ilam University, Ilam, Iran.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran

    Mohsen Nikoorazm, Arash Ghorbani-Choghamarani & Arida Jabbari

Authors
  1. Mohsen Nikoorazm
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  2. Arash Ghorbani-Choghamarani
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  3. Arida Jabbari
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Correspondence to Mohsen Nikoorazm.

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Nikoorazm, M., Ghorbani-Choghamarani, A. & Jabbari, A. A facile preparation of palladium Schiff base complex supported into MCM-41 mesoporous and its catalytic application in Suzuki and Heck reactions. J Porous Mater 23, 967–975 (2016). https://doi.org/10.1007/s10934-016-0154-7

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  • DOI: https://doi.org/10.1007/s10934-016-0154-7

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