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Influence of Nano-Ag Addition on Phase Formation and Electrical Properties of (Cu0.5Tl0.5)-1223 Superconducting Phase

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Abstract

Superconducting samples of type (nano-Ag) x Cu0.5Tl0.5Ba2Ca2Cu3O10−δ , x=0.0, 0.5, 1.0, 1.5, 2.0 and 3.0 wt.%, were prepared under ambient pressure via a single step solid-state reaction technique at 850 °C. The prepared samples were characterized by means of X-ray powder diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray (EDX) and differential scanning calorimetry (DSC). The electrical properties of the prepared samples were investigated using the electrical resistivity and IV measurements. The low addition of nano-Ag up to x=1.5 wt.% enhanced the phase formation and improved the superconducting transition temperature T c , critical current density J c , and melting temperature. For x>1.5 wt.%, a reverse trend was observed.

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Acknowledgements

The author of the present study wish to express their thanks to the superconductivity and metallic glass lab, Physics Department, Faculty of Science, Alexandria University, Alexandria, Egypt, for aiding with the experimental procedures.

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Correspondence to R. Awad.

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Abdeen, W., Mohammed, N.H., Awad, R. et al. Influence of Nano-Ag Addition on Phase Formation and Electrical Properties of (Cu0.5Tl0.5)-1223 Superconducting Phase. J Supercond Nov Magn 26, 623–631 (2013). https://doi.org/10.1007/s10948-012-1803-y

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  • DOI: https://doi.org/10.1007/s10948-012-1803-y

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