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Preferential Solvation in Mixed Solvents

13. Mixtures of Tetrahydrofuran with Organic Solvents: Kirkwood–Buff Integrals and Volume-Corrected Preferential Solvation Parameters

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Abstract

The Kirkwood–Buff integrals and the volume-corrected preferential solvation parameters for the first solvation shell of binary mixtures of tetrahydrofuran with many organic solvents, calculated from reported thermodynamic data at the temperatures for which these data were available, are reported. The co-solvents include c-hexane, methyl-c-hexane, n-heptane, i-octane, benzene, toluene, ethylbenzene, 1-chlorobutane, dichloromethane, 1,2-dichloroethane, chloroform, 1,1,1-trichloroethane, tetrachlorom-ethane, tetrachloroethene, hexafluoro benzene, ethanol, 1-propanol, 2-propanol, dibutyl ether, acetic acid, acetone, dimethyl sulfoxide, tetramethylene sulfone (sulfolane), acetonitrile, pyrrolidine, and triethylamine. The preferential solvation parameters of these mixtures are discussed in terms of the interactions that occur.

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  1. Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem, 91904, Israel

    Yizhak Marcus

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Marcus, Y. Preferential Solvation in Mixed Solvents. J Solution Chem 35, 251–277 (2006). https://doi.org/10.1007/s10953-006-9366-9

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