Skip to main content
SpringerLink
Log in

Periodate Influencing Diperiodatocuprate(III) Oxidation of Sulfur Containing Amino Acid in Aqueous Alkaline Medium

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The diperiodatocuprate(III) (DPC) oxidation of DL-methionine, a sulfur containing amino acid, was studied spectrophotometrically in alkaline solution. The reaction rate was first order in the concentration of DPC and fractional order in the concentration of DL-methionine. Increasing the OH− concentration decreased the rate of reaction, whereas adding IO −4 enhanced the rate. The reaction was preceded by a small initiation period of about 0.8 minutes. This initiation time decreased when the concentration of IO −4 or DPC increased. Adding the reaction products did not alter the rate of reaction. A mechanism including the intervention of a DL-methionine free radical is proposed and the corresponding rate law is derived. The reaction rate constants are evaluated as well as the activation parameters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Malaprade, L.: Synthesis and characterization of copper(III) periodate complex. Compt. Rend. Acad. Sci., Paris 204, 979–980 (1937)

    CAS  Google Scholar 

  2. Sethuram, B.: Some Aspects of Electron Transfer Reactions Involving Organic Molecules. Allied Publishers (P) Ltd., New Delhi (2003)

    Google Scholar 

  3. Rozovskii, G.I., Juktonis, S., Junkauskas, R., Noskus, P.: Use of diperiodatocupprate(III) in photometric analysis. Zh. Anal. Khim. 27, 2214–2218 (1972)

    CAS  Google Scholar 

  4. Lister, M.W.: The stability of some complexes of trivalent copper. Can. J. Chem. 31, 638–652 (1953)

    Article  CAS  Google Scholar 

  5. Jaiswal, P.K.: Micro determination of formic oxalic and acetic acid in their mixture by selective oxidation. Zh. Anal. Chem. 263, 335–336 (1973)

    Article  CAS  Google Scholar 

  6. Williamson, W.H., Fromm, H.I.: The incorporation of sulfur amino acids into the proteins of regenerating wound tissue. J. Biol. Chem. 212, 705–712 (1955)

    CAS  Google Scholar 

  7. National Center for Health Statistics. Department of Health and Human Services Publ., USA (1991)

  8. Jaiswal, P.K., Yadava, K.L.: Determination of sugars and organic acids with periodate complex of Cu(III). Ind. J. Chem. 11, 837–838 (1973)

    CAS  Google Scholar 

  9. Murthy, C.P., Sethuram, B., Navaneeth Rao, T.: Kinetics of oxidations of some alcohols by diperiodato cuprate(III) in alkaline medium. Z. Phys. Chem. 262, 336–340 (1981)

    CAS  Google Scholar 

  10. Feigl, F.: Spot Tests in Organic Analysis. Elsevier, New York (1975)

    Google Scholar 

  11. Goswami, K.B., Chandra, G., Srivastava, S.N.: Mechanism of oxidation of methionine by iron(III)-1,10-phenanthroline. J. Indian Chem. Soc. 58, 252–258 (1981)

    CAS  Google Scholar 

  12. Lide, D.R.: Handbook of Chemistry and Physics, 73rd edn. CRC, London (1992)

    Google Scholar 

  13. Rozovski, G.I., Prokopchik, A.Yu., Jankauskas, R.: Copper(II) oxidation to the trivalent state by periodate. Liet. TSR Mokslu̧ Acad. Dart. Ser. B 1, 25–34 (1968)

    Google Scholar 

  14. Rozovski, G.I., Prokopchik, A.Yu., Jankauskas, R.: Chem. Abstr. 70, 25355 (1968)

    Google Scholar 

  15. Jensovsky, L., Milos Rabe, K.: Magnelishe Eigen einiger komplexe der dreiwertigen kupters silbers und goldes. Z. Anorg. Allegem. Chem. 314, 76–79 (1962)

    Article  CAS  Google Scholar 

  16. Murthy, C.P., Sethuram, B., Navaneetha Rao, T.: Kinetics of oxidations of some alcohols by diperiodato cuprate(III) in alkaline medium. Z. Phys. Chem. (Leipzig) 262, 336–340 (1981)

    CAS  Google Scholar 

  17. Crouthumel, C.E., Meck, H.V., Martin, D.S., Banks, C.V.: Spectrophotometric studies of dilute aqueous periodato solutions. J. Am. Chem. Soc. 71, 3031–3035 (1949)

    Article  Google Scholar 

  18. Crouthumel, C.E., Hayes, A.M., Martin, B.S.: Ionization hydration equilibria of periodic acid. J. Am. Chem. Soc. 73, 82–87 (1951)

    Article  Google Scholar 

  19. Tuwar, S.M., Nandibewoor, S.T., Raju, J.R.: Oxidation of allyl alcohol by diperiodatonickelate(IV) in aqueous alkaline medium. J. Indian Chem. Soc. 69, 651–653 (1992)

    CAS  Google Scholar 

  20. Balreddy, K., Sethuram, B., Navaneeth Rao, T.: Kinetics of Rh(III)-catalyzed oxidation of some alcohols by diperiodatocuprate(III) in aqueous alkaline medium. Indian J. Chem. 27, 730–731 (1988)

    Google Scholar 

  21. Bell, R.P., Ramsden, E.N.: Kinetics of bromination of some aromatic amines. J. Chem. Soc. 161–167 (1958)

  22. Chang, R.: Physical Chemistry with Application to Biological System, p. 326. Macmillan, New York (1981)

    Google Scholar 

  23. Laidler, K.J.: Chemical Kinetics, 3rd edn., p. 195. Pearson Education, Singapore (2004)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Karnatak Science College, Dharwad, 580001, India

    K. Sharanabasamma, Manjali S. Salunke & Suresh M. Tuwar

Authors
  1. K. Sharanabasamma
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Manjali S. Salunke
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Suresh M. Tuwar
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Suresh M. Tuwar.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sharanabasamma, K., Salunke, M.S. & Tuwar, S.M. Periodate Influencing Diperiodatocuprate(III) Oxidation of Sulfur Containing Amino Acid in Aqueous Alkaline Medium. J Solution Chem 37, 1217–1225 (2008). https://doi.org/10.1007/s10953-008-9307-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-008-9307-x

Keywords

Search

Navigation