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Thermodynamic, Dielectric and Conformational Studies on Hydrogen Bonded Binary Mixtures of Propan-1-ol with Methyl Benzoate and Ethyl Benzoate

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Abstract

Dielectric relaxation studies of propan-1-ol with alkyl benzoates (methyl benzoate and ethyl benzoate) have been carried out, for various mole fractions, at different temperatures using a LF impedance analyzer, Plunger method, and an Abbe’s refractometer in the radio, microwave and optical frequency regions, respectively. Kirkwood’s effective correlation factor, the corrective Kirkwood correlation factor, Bruggeman parameter, relaxation time, excess inverse relaxation time and thermodynamic parameters were calculated using the experimental data. Conformational analysis of the formation of hydrogen bonds in the equi-molar binary mixtures of propan-1-ol with alkyl benzoates is supported by experimental and theoretical FT-IR values.

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Authors and Affiliations

  1. Department of Physics, Acharya Nagarjuna University, Nagarjunanagar, 522510, India

    T. Madhu Mohan & S. Sreehari Sastry

  2. Department of Physics, Indian Institute of Technology, Chennai, 600036, India

    V. R. K. Murthy

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  1. T. Madhu Mohan
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  2. S. Sreehari Sastry
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  3. V. R. K. Murthy
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Correspondence to T. Madhu Mohan.

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Mohan, T.M., Sastry, S.S. & Murthy, V.R.K. Thermodynamic, Dielectric and Conformational Studies on Hydrogen Bonded Binary Mixtures of Propan-1-ol with Methyl Benzoate and Ethyl Benzoate. J Solution Chem 40, 131–146 (2011). https://doi.org/10.1007/s10953-010-9634-6

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  • DOI: https://doi.org/10.1007/s10953-010-9634-6

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