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Polyaniline coated magnetic carboxymethylcellulose beads for selective removal of uranium ions from aqueous solution

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Abstract

Magnetic carboxymethylcellulose (CMC) beads were prepared via ionic cross-linking. Then CMC beads were coated with polyaniline (PANI). The results of FTIR, SEM, DTA and N2 adsorption–desorption demonstrated that aniline was successfully grafted onto the surface of mCMC beads. The potential use of the prepared adsorbent was used for removal of U(VI) ions. The determined maximum adsorption capacities of the mCMC and mCMC-g-PANI beads for U(VI) ions were 129.4 and 386.5 mg/g dry weight at pH 4.5, respectively. The thermodynamic parameters (ΔH°, ΔS° and ΔG°) were evaluated. The adsorbent systems were regenerated using 0.1 M HCl.

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Authors and Affiliations

  1. Biochemical Processing and Biomaterial Research Laboratory, Gazi University, 06500, Teknikokullar, Ankara, Turkey

    M. Yakup Arica & Gulay Bayramoglu

  2. Department of Chemistry, Faculty of Science, Gazi University, 06500, Teknikokullar, Ankara, Turkey

    Gulay Bayramoglu

Authors
  1. M. Yakup Arica
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  2. Gulay Bayramoglu
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Correspondence to Gulay Bayramoglu.

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Arica, M.Y., Bayramoglu, G. Polyaniline coated magnetic carboxymethylcellulose beads for selective removal of uranium ions from aqueous solution. J Radioanal Nucl Chem 310, 711–724 (2016). https://doi.org/10.1007/s10967-016-4828-z

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  • DOI: https://doi.org/10.1007/s10967-016-4828-z

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