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Synthesis, TG, DSC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4

A precursor for NiMn2O4 nanoparticles

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Abstract

Nickel manganese succinato-hydrazinate (NiMn2(C4H4O4)3·6N2H4), has been synthesized for the first time by a novel precursor technique and characterized by IR, AAS and XRD. Thermal decomposition of the compound was studied from room temperature (rT) to 800°C by differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis besides isothermal mass loss studies. The compound was found to decompose autocatalytically, once ignited. TG-DSC shows two steps decomposition i.e. dehydrazination followed by decarboxylation. The infrared spectral studies show the N–N stretching frequency at 972 cm–1 suggesting a bidentate bridging structure of hydrazine molecule in (NiMn2(C4H4O4)3·6N2H4).

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Authors and Affiliations

  1. Department of Chemistry, Goa University, Goa, India, 403206

    Reema A. Porob

  2. Institut für Mechanische Verfahrenstechnik und Mechanik, Universität Karlsruhe (TH), Karlsruhe, Germany, 76128

    Sitara Z. Khan

  3. Institute for Research in Construction, National Research Council Canada, Ottawa, Canada, K1A 0R6, ON, M-20, 1200 Montreal Road

    S. C. Mojumdar

  4. Institut für Technische Chemie und Polymerchemie, Universität Karlsruhe (TH), Karlsruhe, Germany, 76128

    V. M. S. Verenkar

Authors
  1. Reema A. Porob
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  2. Sitara Z. Khan
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  3. S. C. Mojumdar
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  4. V. M. S. Verenkar
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Correspondence to S. C. Mojumdar.

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Porob, R.A., Khan, S.Z., Mojumdar, S.C. et al. Synthesis, TG, DSC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4 . J Therm Anal Calorim 86, 605–608 (2006). https://doi.org/10.1007/s10973-006-7715-y

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  • DOI: https://doi.org/10.1007/s10973-006-7715-y

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