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Multifunctional Cu(II) organic–inorganic hybrid as a catalyst for Knoevenagel condensation

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Abstract

In this study, organic–inorganic hybrid materials based on polyoxometalate and copper coordination polymer, [CuI(4,4′-bipy)]3[PMo VI10 Mo V2 O40{CuII(2,2′-bipy)}] designated as CuMo-CP(1), were prepared and characterized by various techniques including X-ray powder diffraction (XRD), infrared spectroscopy (FT-IR), and elemental analysis. It was found that the CuMo-CP(1) can be used as an efficient heterogeneous bifunctional acid-base catalyst for Knoevenagel condensation of aromatic aldehydes and cyclohexanone with malononitrile or ethyl cyanoacetate at 60 °C in ethanol. Obtaining the corresponding Knoevenagel adduct in moderate to excellent conversion yields within 4 h is promising. The catalyst can be easily recovered from the reaction mixture and reused for three times without significant loss of activity.

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Acknowledgments

The authors would appreciate the Alzahra University for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, Vanak, P.O. Box 1993891176, Tehran, Iran

    Faezeh Farzaneh & Mahtab Kashani Maleki

  2. School of Chemistry, College of Science, University of Tehran, P.O. Box 14155 6455, Tehran, Iran

    Mehdi Ghandi

Authors
  1. Faezeh Farzaneh
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  2. Mahtab Kashani Maleki
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  3. Mehdi Ghandi
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Correspondence to Faezeh Farzaneh.

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Farzaneh, F., Kashani Maleki, M. & Ghandi, M. Multifunctional Cu(II) organic–inorganic hybrid as a catalyst for Knoevenagel condensation. Reac Kinet Mech Cat 117, 87–101 (2016). https://doi.org/10.1007/s11144-015-0919-z

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  • DOI: https://doi.org/10.1007/s11144-015-0919-z

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