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Five-component domino synthesis of tetrahydropyridines using hexagonal PbCr x Fe12−x O19 as efficient magnetic nanocatalyst

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Abstract

Hexagonal PbCr x Fe12−x O19 nanostructures were prepared through a sol–gel autocombustion (SGAC) method using malonic acid as fuel. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) analysis, and vibrating-sample magnetometry were used as tools to study the structure, morphology, and composition of the nanostructures. The optimal product was further evaluated as a reusable magnetic catalyst in a five-component reaction for synthesis of highly functionalized tetrahydropyridines (HF-THP). All reactions completed in short time and all products were obtained in good yield in presence of the magnetic nanocatalyst. Besides, it was found that PbCr x Fe12−x O19 could be recovered five times, without any noticeable loss in catalytic activity.

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Acknowledgements

Authors are grateful to council of University of Arak, University of Tehran and University of Imam Hossein for supporting this work.

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Authors and Affiliations

  1. Young Researchers and Elites Club, Arak Branch, Islamic Azad University, Arak, Iran

    Ali Sobhani-Nasab

  2. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Abolfazl Ziarati & Alireza Badiei

  3. Faculty of Pharmacy, Baqiyatallah University of Medical Sciences, Tehran, Iran

    Mehdi Rahimi-Nasrabadi

  4. Department of Chemistry, Imam Hossein University, Tehran, Iran

    Mehdi Rahimi-Nasrabadi

  5. Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran

    Mohammad Reza Ganjali

Authors
  1. Ali Sobhani-Nasab
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  2. Abolfazl Ziarati
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  3. Mehdi Rahimi-Nasrabadi
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  4. Mohammad Reza Ganjali
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  5. Alireza Badiei
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Correspondence to Mehdi Rahimi-Nasrabadi.

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Sobhani-Nasab, A., Ziarati, A., Rahimi-Nasrabadi, M. et al. Five-component domino synthesis of tetrahydropyridines using hexagonal PbCr x Fe12−x O19 as efficient magnetic nanocatalyst. Res Chem Intermed 43, 6155–6165 (2017). https://doi.org/10.1007/s11164-017-2982-8

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