Abstract
β-Enaminone and its derivatives have emerged among the finest bioactive intermediates. High yields of several β-enaminones (86–97%) are achieved through treatment of substituted aromatic and aliphatic amines with cyclic/acyclic 1,3-diketones, over the magnetically separable cobalt ferrite nanoparticles (CoFe2O4 NPs). The latter was prepared upon co-precipitation. Its purity, fine crystallinity, elemental distributions, morphology, magnetic features, and thermal stability were confirmed by Fourier transform infrared, X-ray diffraction, energy dispersive X-ray spectrometry, scanning electron microscopy, vibrating sample magnetometry, and thermal gravimetric analysis analyses. Thus, CoFe2O4 NPs acted as an excellent green heterogeneous nanocatalyst for synthesis of β-enaminones and gave good recyclability, while showing insignificant loss of their activity.
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Eidi, E., Kassaee, M.Z. & Cummings, P.T. β-Enaminones over recyclable nano-CoFe2O4: a highly efficient solvent-free green protocol. Res Chem Intermed 44, 5787–5799 (2018). https://doi.org/10.1007/s11164-018-3454-5
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DOI: https://doi.org/10.1007/s11164-018-3454-5