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Synthesis and characterization of spinel FeAl2O4 (hercynite) magnetic nanoparticles and their application in multicomponent reactions

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Abstract

The spinel ferrite FeAl2O4 (hercynite) MNPs (magnetic nanoparticles) were applied as a reusable catalytic system for the one-pot synthesis of benzo[a]pyrano[2,3-c] phenazine and polyhydroquinoline derivatives via a multicomponent reaction under green reaction conditions. The structure of the prepared nanocatalyst has been characterized by XRD, FTIR, SEM, EDS, BET, and VSM techniques. The FeAl2O4 MNPs act as Lewis acids and offer several advantages such as high yields of products, short reaction times, and easy workup procedure. Moreover, the recycled nanocatalyst was used at least four times without significant loss of its activity.

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Acknowledgements

The authors thank the research facilities of Ilam University, Ilam, Iran, for financial support of this research project.

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  1. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran

    Arash Ghorbani-Choghamarani, Masoud Mohammadi, Lotfi Shiri & Zahra Taherinia

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  1. Arash Ghorbani-Choghamarani
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Correspondence to Arash Ghorbani-Choghamarani.

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Ghorbani-Choghamarani, A., Mohammadi, M., Shiri, L. et al. Synthesis and characterization of spinel FeAl2O4 (hercynite) magnetic nanoparticles and their application in multicomponent reactions. Res Chem Intermed 45, 5705–5723 (2019). https://doi.org/10.1007/s11164-019-03930-0

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