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Gas phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene

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Abstract

The results of time resolved gas phase studies of labile germylenes (GeH2 and GeMe2) and dimethylstannylene (SnMe2) reactions reported to date are considered together with data of quantum-chemical investigations of the potential energy surfaces of these systems. Reaction mechanisms are discussed. A comparison of reactivity in the series of carbene analogs, ER2 (E = Si, Ge, Sn, R = H, Me), is made.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991, Moscow, Russian Federation

    S. E. Boganov, M. P. Egorov, V. I. Faustov, I. V. Krylov & O. M. Nefedov

  2. Instituto de Quimica Fisica “Rocasolano”, C. S. I. C., C/Serrano 119, 28006, Madrid, Spain

    R. Becerra

  3. Department of Chemistry, University of Reading, Whiteknights, P. O. Box 224, Reading, RG6 6AD, UK

    R. Walsh

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  1. S. E. Boganov
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  2. M. P. Egorov
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  3. V. I. Faustov
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  4. I. V. Krylov
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  5. O. M. Nefedov
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  6. R. Becerra
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 477–505, March, 2005.

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Boganov, S.E., Egorov, M.P., Faustov, V.I. et al. Gas phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene. Russ Chem Bull 54, 483–511 (2005). https://doi.org/10.1007/s11172-005-0285-5

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  • DOI: https://doi.org/10.1007/s11172-005-0285-5

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