Abstract
Cycloaddition reactions of norbornadiene with fluorinated heteroaddends (hexafluoro-acetone, dichlorotetrafluoroacetone, trifluoroacetonitrile, and N-trifluoroacetylhexafluoro-propan-2-imine) were studied. As a rule, the reactions follow the concerted mechanism. The reaction with bis(trifluoromethyl)ketene gave a mixture of tricyclene [2+2]- and [2+2+2]-cyclo-adducts formed along different pathways.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 1013–1015, April, 2005.
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Vasil'ev, N.V., Truskanova, T.D., Buzaev, A.V. et al. Cycloaddition of norbornadiene to fluorine-containing heteroaddends. Russ Chem Bull 54, 1038–1040 (2005). https://doi.org/10.1007/s11172-005-0353-x
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DOI: https://doi.org/10.1007/s11172-005-0353-x