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Synthesis of photochromic benzopyrans annulated by 15(18)-crown-5(6) ether

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Abstract

The reaction of hydroxy-substituted benzo-15(18)-crown-5(6) ether or benzo-18-crown-6 ether with β-phenylcinnamaldehyde in the presence of titanium tetraethoxide yielded crown-annulated 2,2-diphenylbenzopyrans. The compounds are photochromic, and the spectral characteristics of their colored form are unusual for this class of chromenes.

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Authors and Affiliations

  1. D. I. Mendeleev University of Chemistry and Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    S. V. Paramonov, O. A. Fedorova & V. P. Perevalov

  2. Centre Interdisciplinaire de Nanoscience de Marseille (CINaM,CNRS), 163 Av. de Luminy, 13288, Marseille, France

    V. Lokshin & V. Khodorkovsky

Authors
  1. S. V. Paramonov
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  2. O. A. Fedorova
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  3. V. P. Perevalov
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  4. V. Lokshin
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  5. V. Khodorkovsky
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Corresponding author

Correspondence to O. A. Fedorova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2333–2336, November, 2008.

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Paramonov, S.V., Fedorova, O.A., Perevalov, V.P. et al. Synthesis of photochromic benzopyrans annulated by 15(18)-crown-5(6) ether. Russ Chem Bull 57, 2381–2384 (2008). https://doi.org/10.1007/s11172-008-0339-6

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  • DOI: https://doi.org/10.1007/s11172-008-0339-6

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