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New tin(iv) o-iminosemiquinone complexes

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New tin(iv) mono- and bis-o-iminosemiquinone complexes were obtained by the exchange reaction of radical anion lithium salt of 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-imino-benzoquinone with tin(iv) organochlorides. The compounds synthesized were characterized by EPR spectroscopy and X-ray diffraction analysis. Substituents on the tin atom were found to affect stability of paramagnetic metal derivatives formed.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    A. V. Piskunov, I. N. Meshcheryakova, E. V. Baranov, G. K. Fukin, V. K. Cherkasov & G. A. Abakumov

Authors
  1. A. V. Piskunov
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  2. I. N. Meshcheryakova
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  3. E. V. Baranov
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  4. G. K. Fukin
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  5. V. K. Cherkasov
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  6. G. A. Abakumov
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Correspondence to A. V. Piskunov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 354–363, February, 2010.

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Piskunov, A.V., Meshcheryakova, I.N., Baranov, E.V. et al. New tin(iv) o-iminosemiquinone complexes. Russ Chem Bull 59, 361–370 (2010). https://doi.org/10.1007/s11172-010-0087-2

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  • DOI: https://doi.org/10.1007/s11172-010-0087-2

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