Abstract
The radical anion P4·− was detected and identified by the ESR method as a spin-adduct with nitrone during the electrochemical reduction of white phosphorus in the presence of a spin trap, viz., α-phenyl-N-tert-butylnitrone, in a special electrolysis cell with a helical platinum working electrode in the potentiostatic mode. The character of the behavior of P4·− and the spin trap during electrochemical reduction was monitored by cyclic voltammetry directly in the electrolysis cell, and the spin-adduct formed was detected by ESR.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 456–458, February, 2010.
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Kadirov, M.K., Budnikova, Y.G., Kholin, K.V. et al. Spin-adduct of the P4 ·− radical anion during the electrochemical reduction of white phosphorus. Russ Chem Bull 59, 466–468 (2010). https://doi.org/10.1007/s11172-010-0103-6
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DOI: https://doi.org/10.1007/s11172-010-0103-6