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Structure and properties of μ2-S-[bis(benzenethiolato)tetranitrosyldiiron] in solution

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Abstract

Dinuclear iron tetranitrosyl complex with the composition [Fe2(SPh)2(NO)4] (1) was synthesized and its single crystals and polycrystals were studied by X-ray diffraction, IR spectroscopy, and elemental analysis. The decomposition products of complex 1 were investigated by electrochemical method and mass spectrometry. The mass spectrum of a solution of complex 1 shows two groups of ions: the primary decomposition products of 1 in solution (the complex ions [Fe(SPh)(NO)2(NO2)]−, [Fe(SPh)2(NO)]−, and [Fe(SPh)2(NO)2]−) and a series of the ions [FeO2 + n(NO)]− and [FeO3 + n(NO)]− (n = 0–4), which are formed in secondary reactions. The structures of the complexes, which were formed through the Fe-NO bond dissociation and the replacement of the NO ligand by aqua and oxygen ligands in complex 1, and the structure of the complex [FeO3]− were studied by quantum chemical modeling.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    N. A. Sanina, N. S. Emel’yanova, A. N. Chekhlov, A. F. Shestakov & S. M. Aldoshin

  2. Institute of Energy Problems for Chemical Physics (Branch), Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    I. V. Sulimenkov

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  1. N. A. Sanina
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  2. N. S. Emel’yanova
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  3. A. N. Chekhlov
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  4. A. F. Shestakov
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  5. I. V. Sulimenkov
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  6. S. M. Aldoshin
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Correspondence to N. A. Sanina.

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Dedicated to Academician I. L. Eremenko on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1104–1114, June, 2010.

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Sanina, N.A., Emel’yanova, N.S., Chekhlov, A.N. et al. Structure and properties of μ2-S-[bis(benzenethiolato)tetranitrosyldiiron] in solution. Russ Chem Bull 59, 1126–1136 (2010). https://doi.org/10.1007/s11172-010-0215-z

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  • DOI: https://doi.org/10.1007/s11172-010-0215-z

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