Skip to main content
SpringerLink
Log in

Investigation of cobalt (1,10-phenanthroline)-bis-(3,6-di-tert-butyl-o-benzosemiquinolate) by X-ray diffraction, IR and ESR spectroscopy, magnetochemistry, and precision calorimetry

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The bistable cobalt complex containing two symmetrical 3,6-di-tert-butyl-o-benzoquinone and one 1,10-phenanthroline moieties as ligands (1) was synthesized. Complex 1 was isolated in the individual state and characterized by IR and ESR spectroscopy, X-ray diffraction, magnetochemical studies, and precision calorimetry. A change in temperature causes the reversible metal-ligand electron transfer and spin crossover (redox isomerism) in complex 1 in the crystalline state. The redox-isomeric transformation at ∼250 K is accompanied by the phase transition. The structural study at two temperatures confirmed the changes in the molecular and crystal structure associated with the redox-isomeric transformation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. A. Abakumov, V. K. Cherkasov, M. P. Bubnov, O. G. Ellert, Zh. V. Dobrokhotova, L. N. Zakharov, Yu. T. Struchkov, Dokl. Akad. Nauk, 1993, 328, 332 [Dokl. Chem. (Engl. Transl.), 1993].

    CAS  Google Scholar 

  2. D. M. Adams, A. Dei, A. L. Rheingold, D. N. Hendrickson, Angew. Chem., Int. Ed. Engl., 1993, 32, 880.

    Article  Google Scholar 

  3. D. M. Adam, A. Dei, A. L. Rheingold, D. N. Hendrickson, J. Am. Chem. Soc., 1993, 115, 8211.

    Google Scholar 

  4. D. N. Hendrickson, C. G. Pierpont, Top. Curr. Chem., 2004, 234, 63.

    CAS  Google Scholar 

  5. Y. Mulyana, G. Poneti, B. Moubaraki, K. S. Murray, B. F. Abrahams, L. Sorace, C. Boskovi, Dalton Trans., 2010, 39, 4757.

    Article  CAS  Google Scholar 

  6. D. Adams, D. N. Hendrickson, J. Am. Chem. Soc., 1996, 118, 11515.

    Article  CAS  Google Scholar 

  7. Osamu Sato, Jun Tao, Yuan-Zhu Zhang, Angew. Chem., Int. Ed., 2007, 46, 2152.

    Article  CAS  Google Scholar 

  8. Ok-Sang Jung, Du Hwan Jo, Young-A Lee, B. J. Conklin, C. G. Pierpont, Inorg. Chem., 1997, 36, 19.

    Article  CAS  Google Scholar 

  9. B. V. Lebedev, N. N. Smirnova, G. A. Abakumov, V. K. Cherkasov, M. P. Bubnov, J. Chem. Thermodynamics, 2002, 34, 2093.

    Article  CAS  Google Scholar 

  10. S. Attia, C. G. Pierpont, Inorg. Chem., 1997, 36, 6184.

    Article  CAS  Google Scholar 

  11. C. Roux, D. M. Adams, J. P. Itie, A. Polian, D. N. Hendrickson, M. Verdaguer, Inorg. Chem., 1996, 35, 2846.

    Article  CAS  Google Scholar 

  12. I. N. Markevtsev, M. P. Monakhov, V. V. Platonov, A. S. Mischenko, A. K. Zvezdin, G. A. Abakumov, V. K. Cherkasov, J. Magnetism Magnetic Materials, 2006, 300, No. 1, e407.

    Article  CAS  Google Scholar 

  13. D. Ruiz, J. You, I. A. Guzei, A. L. Rheingold, D. N. Hendrickson, Chem. Commun., 1998, 2089.

  14. A. V. Arapova, M. P. Bubnov, G. A. Abakumov, V. K. Cherkasov, N. A. Skorodumova, N. N. Smirnova, Zh. Fiz. Khim., 2009, 83, 1417 [Russ. J. Phys. Chem. (Engl. Transl.), 2009, 83].

    Google Scholar 

  15. G. A. Abakumov, M. P. Bubnov, V. K. Cherkasov, N. A. Skorodumova, A. V. Arapova, N. N. Smirnova, Zh. Fiz. Khim. A, 2008, 82, 172 [Russ. J. Phys. Chem. (Engl. Transl.), 2008, 82].

    CAS  Google Scholar 

  16. A. Beni, A. Dei, S. Laschi, M. Rizzitano, L. Sorace, Chem. Eur. J., 2008, 14, 1804.

    Article  CAS  Google Scholar 

  17. C. Carbonera, A. Dei, J.-F. Le’tard, C. Sangregorio, L. Sorace, Angew. Chem., Int. Ed., 2004, 43, 3136.

    Article  CAS  Google Scholar 

  18. I. Imaz, D. Maspoch, C. Rodrigez-Blanco, J. M. PerezFalcon, J. Campo, D. Ruiz-Molina, Angew. Chem., Int. Ed., 2008, 47, 1857.

    Article  CAS  Google Scholar 

  19. S. Bin-Salamon, S. Brewer, S. Franzen, D. L. Feldheim, S. Lappi, D. A. Shultz, J. Am. Chem. Soc., 2005, 127, 5328.

    Article  CAS  Google Scholar 

  20. D. Kiriya, Ho-Chol Chang, A. Kamata, S. Kitagawa, Dalton Trans., 2006, 1377.

  21. D. Kiriya, Ho-Chol Chang, S. Kitagawa, J. Am. Chem. Soc., 2008, 130, 5515.

    Article  CAS  Google Scholar 

  22. T. J. O’sullivan, B. Djukic, P. A. Dubeb, M. T. Lemaire, Chem. Commun., 2009, 1903.

  23. Ok-Sang Jung, Cortland G. Pierpont, J. Am. Chem. Soc., 1994, 116, 1127.

    Article  CAS  Google Scholar 

  24. G. A. Abakumov, V. K. Cherkasov, M. P. Bubnov, L. G. Abakumova, L. N. Zakharov, G. K. Fukin, Izv. Akad. Nauk, Ser. Khim., 1999, 1784 [Russ. Chem. Bull. (Engl. Transl.), 1999, 48, 1762].

    Google Scholar 

  25. B. V. Lebedev, Thermochim. Acta, 1997, 297, 143.

    Article  CAS  Google Scholar 

  26. R. M. Buchanan, C. G. Pierpont, Coord. Chem. Rev., 1981, 38, 45.

    Article  Google Scholar 

  27. G. A. Abakumov, V. K. Cherkasov, M. P. Bubnov, O. G. Ellert, Yu. V. Rakitin, L. N. Zakharov, Yu. T. Struchkov, Yu. N. Saf’yanov, Izv. Akad. Nauk, Ser. Khim., 1992, 2315 [Bull. Russ. Acad. Sci., Div. Chem. Sci. (Engl. Transl.), 1992, 41, 1813].

    Google Scholar 

  28. D. M. Adams, L. Noodleman, D. N. Hendrickson, Inorg. Chem., 1997, 36, 3966.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    M. P. Bubnov, N. A. Skorodumova, A. V. Arapova, K. A. Kozhanov, G. A. Abakumov & V. K. Cherkasov

  2. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    A. S. Bogomyakov & G. V. Romanenko

  3. Research Institute of Chemistry, N. I. Lobachevsky State University of Nizhny Novgorod, 23/5 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    N. N. Smirnova

Authors
  1. M. P. Bubnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Skorodumova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Bogomyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. V. Romanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Arapova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. K. A. Kozhanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. N. N. Smirnova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. G. A. Abakumov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. V. K. Cherkasov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. P. Bubnov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 440–446, March, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bubnov, M.P., Skorodumova, N.A., Bogomyakov, A.S. et al. Investigation of cobalt (1,10-phenanthroline)-bis-(3,6-di-tert-butyl-o-benzosemiquinolate) by X-ray diffraction, IR and ESR spectroscopy, magnetochemistry, and precision calorimetry. Russ Chem Bull 60, 449–455 (2011). https://doi.org/10.1007/s11172-011-0071-5

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-011-0071-5

Key words

Search

Navigation