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A convenient synthesis and spatial structure of 2-aryl-2-oxo-2-phenylbenzo[e]-1,4,2-oxazaphosphinanes

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Abstract

Phosphorylation of 2-arylideneaminophenol with dichlorophenylphosphine in the presence of triethylamine and subsequent treatment with water led to stereoisomeric derivatives of 3-aryl-2-oxo-2-phenylbenzo[e]-1,4,2-oxazaphosphinanes, which were separated by column chromatography to the individual diastereomers. The structure of stereoisomers was established by NMR spectroscopy and X-ray crystallography.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    M. N. Dimukhametov, V. F. Mironov, E. V. Mironova, D. B. Krivolapov, A. B. Dobrynin, I. A. Litvinov & R. Z. Musin

Authors
  1. M. N. Dimukhametov
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  2. V. F. Mironov
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  3. E. V. Mironova
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  4. D. B. Krivolapov
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  5. A. B. Dobrynin
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  6. I. A. Litvinov
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  7. R. Z. Musin
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Corresponding author

Correspondence to V. F. Mironov.

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Dedicated to the memory of Corresponding Member of the Russian Academy of Sciences M. Yu. Antipin (1951–2013).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1882–1891, August, 2013.

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Dimukhametov, M.N., Mironov, V.F., Mironova, E.V. et al. A convenient synthesis and spatial structure of 2-aryl-2-oxo-2-phenylbenzo[e]-1,4,2-oxazaphosphinanes. Russ Chem Bull 62, 1882–1891 (2013). https://doi.org/10.1007/s11172-013-0271-2

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  • DOI: https://doi.org/10.1007/s11172-013-0271-2

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