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Association of ionic surfactant in binary water—ethanol media as indicator of changes in structure and properties of solvent

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Abstract

Association of sodium dodecyl sulfate (SDS) ionic surfactant in concentration range of 1–100 mmol L−1 in binary water—ethanol media with alcohol volume concentrations of 0–92.3 vol.% was studied by conductometry and nuclear magnetic resonance spectrometry. The dynamic properties of surfactant solutions including self-diffusion processes and diffusive transfer of charges in SDS solutions under alteration of solvent micro-heterogeneous structure were studied. The transformation of structure and size of SDS associates upon change of ethanol content in the solution was discussed. The correlation between SDS association processes and changes in micro-heterogeneous structure of binary solvent was analyzed.

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Authors and Affiliations

  1. Kazan State Power Engineering University, 51 Krasnoselskaya ul., 420066, Kazan, Russian Federation

    O. S. Zueva

  2. Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center of Russian Academy of Sciences, 2/31 ul. Lobachevskogo, 420111, Kazan, Russian Federation

    A. O. Makarova, B. I. Khairutdinov, Yu. F. Zuev & A. N. Turanov

Authors
  1. O. S. Zueva
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  2. A. O. Makarova
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  3. B. I. Khairutdinov
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  4. Yu. F. Zuev
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Correspondence to Yu. F. Zuev.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. N. Charushin on the occasion of his 70th birthday.

Published in Russian in Izyestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1185–1190, June, 2021.

The work was carried out within the framework of the state assignment of the Kazan Scientific Center of the Russian Academy of Sciences (conductometry, A. O. Makarova; NMR experiments, A. N. Turanov and B. I. Khairutdinov; general analysis of the results, O. S. Zueva and Yu. F. Zuev).

The authors are grateful to the Center for Shared Use of the Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences” for the opportunity to carry out NMR experiments.

This paper does not contain description of studies or animals or humans.

The authors declare no conflicts of interests.

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Zueva, O.S., Makarova, A.O., Khairutdinov, B.I. et al. Association of ionic surfactant in binary water—ethanol media as indicator of changes in structure and properties of solvent. Russ Chem Bull 70, 1185–1190 (2021). https://doi.org/10.1007/s11172-021-3203-6

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  • DOI: https://doi.org/10.1007/s11172-021-3203-6

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