Skip to main content
SpringerLink
Log in

Ion Selective Electrode Determination of Free Versus Total Fluoride Ion in Simple and Fluoroligand Coordinated Hexafluoropnictate (PnF6−, Pn = P, As, Sb, Bi) Salts

  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

Interpretation of the results of determinations of free fluoride (Ff−) and total fluoride (Ft−) obtained with fluoride ISE while conducting elemental chemical analysis of bulk material of newly synthesized inorganic fluoride compounds is of crucial importance for the purpose of determination of purity and stoichiometry of these compounds. Knowledge of the properties and behavior of these compounds in aqueous media is therefore essential. Observations are presented on the determinations of the amounts of Ft− and Ff− in fluorinated compounds, in the particular hexafluoropnictate salts (PnF6−, Pn = P, As, Sb, Bi) as found in aqueous media and in some compounds with XeF2, AsF3 ligands. A critical look at the determined amounts of Ff−, Ft−and calculated amounts of bound fluoride (Fb−) is provided.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Frlec B.; Gantar D.; Holloway J. H. J. Fluorine Chem. 1982, 20, 385.

    Article  Google Scholar 

  2. Gantar D.; Leban I.; Frlec B. J. Chem. Soc., Dalton Trans. 1987, 2379.

  3. Fele-Beuermann M.; Lutar K.; Mazej Z.; Milićev S.; Žemva B. J. Fluorine Chem. 1998, 89, 83.

    Article  Google Scholar 

  4. Tramšek M.; Lork E.; Mews R.; Žemva B. J. Fluorine Chem. 2001, 110, 123.

    Article  Google Scholar 

  5. Turičnik A.; Benkič P.; Žemva B. J. Fluorine Chem. 2003, 121, 245.

    Article  Google Scholar 

  6. Tramšek M.; Benkič P.; Turičnik A.; Tavčar G.; Žemva B. J. Fluorine Chem. 2002, 114, 143.

    Article  Google Scholar 

  7. Turičnik A.; Benkič P.; Žemva B. Inorg. Chem. 2002, 41, 5521.

    Article  PubMed  Google Scholar 

  8. Turičnik A., Ph.D. Thesis, University of Ljubljana, Ljubljana, Slovenia, 2003.

  9. Sedej B. Talanta 1976, 23, 335.

    Article  Google Scholar 

  10. Ponikvar M.; Liebman J. F.; Jenkins H. D. B. Eur. J. Inorg. Chem. 2004, 3273.

  11. Frant, M. S.; Ross J. W., Jr. Science 1966, 154, 1553.

    PubMed  Google Scholar 

  12. Covington A. K. Ion-Selective Electrode Methodology; Vol. 2. CRC Press: Boca Raton, 1979.

  13. Model 94-09, Model 96-09 Fluoride/Fluoride Combination Electrode Instruction Manual; Thermo Orion: Beverly, Massachusetts, 1999.

  14. Frant M. S.; Ross J. W. Jr. Anal. Chem. 1968, 40, 1169.

    Article  PubMed  Google Scholar 

  15. Peters M. A.; Ladd D. M. Talanta 1971, 18, 655.

    Article  Google Scholar 

  16. Ponikvar M.; Žemva B.; Liebman J. F. J. Fluorine Chem. 2003, 123, 217.

    Article  Google Scholar 

  17. Ponikvar M.; Sedej B.; Liebman J. F. Eur. J. Inorg. Chem. 2004, 1349.

  18. Ponikvar M.; Sedej B.; Pihlar B.; Žemva B. Anal. Chim. Acta 2000, 418, 113.

    Article  Google Scholar 

  19. Vogel A. I. Vogel’s Textbook of Quantitative Inorganic Analysis, 4th ed., Longman: London, 1978.

    Google Scholar 

  20. Ponikvar M.; Pihlar B.; Žemva B., J. Fluorine Chem. 2003, 122, 215.

    Article  Google Scholar 

  21. Ponikvar M.; Pihlar B.; Žemva B. Talanta 2002, 58, 803.

    Article  Google Scholar 

  22. Pribil R. Applied Complexometry; Pergamon Press: Oxford, 1982.

    Google Scholar 

  23. Lingane J. J. Analytical Chemistry Of Selected Metallic Elements; Reinhold Publishing Corporation: New York, 1966.

    Google Scholar 

  24. Bartlett N.; Leary K. Rev. Chim. Minér. 1976, 13, 82.

    Google Scholar 

  25. Golič L.; Leban I. Acta Crystallogr. 1977, B33, 232.

    Google Scholar 

  26. O’Donnell T. A., In Comprehensive Inorganic Chemistry; Vol. 5. Bailar, J. C., Jr.; Emeléus, H. J.; Nyholm, R.; Trotman-Dickenson, A. F., (Eds.); Pergamon Press: Oxford, 1973.

  27. Malm J. G.; Holt B. D.; Bane R. W., In Noble-Gas Compounds; Hyman H. H., (Ed.)University of Chicago Press: Chicago, 1963.

  28. Tavčar G.; Benkič P.; Žemva B. Inorg. Chem. 2004, 43, 1452.

    Article  PubMed  Google Scholar 

  29. Hunter E. P.; Lias S. G. J. Phys. Chem. Ref. Data 1998, 27, 413.

    Google Scholar 

  30. Mootz D.; Bartmann K. Z. Naturforsch. 1981, 46B, 1659.

    Google Scholar 

  31. Tramšek M.; Žemva B. J. Fluorine Chem. 2004, 125, 1919.

    Article  Google Scholar 

  32. Tramšek M., Personal communication.

  33. Lutar K.; Borrmann H.; Jesih A.; Žemva B. Acta. Chim. Slov. 1999, 46, 213.

    Google Scholar 

  34. Cotton F. A.; Wilkinson G. Advanced Inorganic Chemistry, 5th ed.Wiley, : New York, 1988.

    Google Scholar 

  35. Griffiths J. E.; Walrafen G. E. Inorg. Chem. 1972, 2, 427.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, Baltimore, Maryland, 21250

    Joel F. Liebman

  2. Jožzef Stefan Institute, Jamova 39, SI-1000, Ljubljana, Slovenia

    Maja Ponikvar

Authors
  1. Joel F. Liebman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Maja Ponikvar
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Maja Ponikvar.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liebman, J.F., Ponikvar, M. Ion Selective Electrode Determination of Free Versus Total Fluoride Ion in Simple and Fluoroligand Coordinated Hexafluoropnictate (PnF6−, Pn = P, As, Sb, Bi) Salts. Struct Chem 16, 521–528 (2005). https://doi.org/10.1007/s11224-005-5179-5

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11224-005-5179-5

Keywords

Search

Navigation