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Steam Reforming of Ethanol on Ferrites

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Theoretical and Experimental Chemistry Aims and scope

The results of the authors’ investigations of steam reforming of ethanol (SRE) on nanosized ferrites with spinel structure MFe2O4 (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) are summarized. The highest yields of the target product hydrogen were obtained on Mg, Mn, and Fe ferrites. A close to stoichiometric yield of H2 was obtained on nanosized MnFe2O4. A probable scheme for the mechanism of SRE, containing redox and acid–base stages, is proposed.

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The authors express their gratitude to I. V. Vasylenko for assistance in the synthesis of the catalysts and for investigating the samples by XRD, electron diffraction, and TEM. The work was conducted with financial support from a comprehensive target program of scientific investigations of the National Academy of Sciences of Ukraine “Fundamental aspects of renewable hydrogen energy and fuel cell technologies.”

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Authors and Affiliations

  1. L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Nauky Ave., 31, Kyiv, 03028, Ukraine

    L. Y. Dolgikh, I. L. Stolyarchuk, L. A. Staraya & Y. I. Pyatnitsky

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  1. L. Y. Dolgikh
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  2. I. L. Stolyarchuk
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  3. L. A. Staraya
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  4. Y. I. Pyatnitsky
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Correspondence to L. Y. Dolgikh.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 54, No. 5, pp. 318-325, September-October, 2018.

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Dolgikh, L.Y., Stolyarchuk, I.L., Staraya, L.A. et al. Steam Reforming of Ethanol on Ferrites. Theor Exp Chem 54, 349–357 (2018). https://doi.org/10.1007/s11237-018-9580-8

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  • DOI: https://doi.org/10.1007/s11237-018-9580-8

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