Skip to main content
SpringerLink
Log in

Two Novel Diamagnetic-metal Coordination Polymers of Nitronyl Nitroxide Radical Incorporating Isophthalate Bridges

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Two novel coordination polymers of formula [Zn(NIT4py)2(ip)]n (1) and [Cd(NIT4py)2(ip)(H2O)]n (2) (NIT4py=2-(4′-pyridinyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide and ip=isophthalate dianion), have been synthesized and determined by X-ray diffraction. The crystal structures of the complexes are both neutral 1-D chains. The Zn(II) ion adopts a distorted tetrahedral geometry and the Cd(II) ion adopts a distorted pentagonal bipyramidal geometry. Each isophthalate dianion binds two metal ions in bis-monodentate mode for complex (1) and in bis-bidentate mode for complex (2) leading to the 1-D chains. In complex (2) the 1-D chains develop into two-dimensional network via the hydrogen bond interactions. The magnetic studies show a weak antiferromagnetic coupling between two radicals through the diamagnetic Zn(II) in complex (1).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M.G.F. Vaz L.M.M. Pinheiro H.O. Stumpf A.F.C. Alcântara S. Golhen L. Ouahab O. Cador C. Mathonière O. Kahn (1999) Chem. Eur. J. 5 1486 Occurrence Handle10.1002/(SICI)1521-3765(19990503)5:5<1486::AID-CHEM1486>3.0.CO;2-F Occurrence Handle1:CAS:528:DyaK1MXjt1Wjtro%3D

    Article  CAS  Google Scholar 

  2. T. Tsukuda, T. Suzuki and S. Kaizaki, J. Chem. Soc., Dalton Trans., 1721 (2002)

  3. K.E. Vostrikova D. Luneau W. Wernsdorfer P. Rey M. Verdaguer (2000) J. Am. Chem. Soc. 122 718 Occurrence Handle10.1021/ja993210o Occurrence Handle1:CAS:528:DC%2BD3cXksVSlsQ%3D%3D

    Article  CAS  Google Scholar 

  4. H. Oshio M. Yamamoto T. Ito (2002) Inorg. Chem. 41 5817 Occurrence Handle10.1021/ic0256112 Occurrence Handle1:CAS:528:DC%2BD38XntVagsr0%3D

    Article  CAS  Google Scholar 

  5. L.Y. Wang B. Zhao C.X. Zhang D.Z. Liao Z.H. Jiang S.P. Yan (2003) Inorg. Chem. 42 5804 Occurrence Handle1:CAS:528:DC%2BD3sXmsFams78%3D

    CAS  Google Scholar 

  6. I. Dasna, S. Golhen, L. Ouahab, O. Peña, J. Guillevic and M. Fettouhi, J. Chem. Soc., Dalton Trans., 129 (2000)

  7. I. Dasna S. Golhen L. Ouahab N. Daro J.P. Sutter (2001) New J. Chem. 25 1572 Occurrence Handle1:CAS:528:DC%2BD3MXovFKgt7g%3D

    CAS  Google Scholar 

  8. L.C. Li Z.L. Liu S.S. Turner D.Z. Liao Z.H. Jiang S.P. Yan (2003) New J. Chem. 27 752 Occurrence Handle1:CAS:528:DC%2BD3sXitlyksr8%3D

    CAS  Google Scholar 

  9. I. Dasna S. Golhen L. Ouahab N. Daro J.P. Sutter (2001) Polyhedron 20 1371 Occurrence Handle10.1016/S0277-5387(01)00621-0 Occurrence Handle1:CAS:528:DC%2BD3MXksV2mtb0%3D

    Article  CAS  Google Scholar 

  10. S.P. Wang D.J. Li Y. Song D.Z. Gao J. Chen Z.Q. Liu D.Z. Liao Z.H. Jiang S.P. Yan (2005) Z. Anorg. Allg. Chem. 631 1702 Occurrence Handle1:CAS:528:DC%2BD2MXlsFymtbk%3D

    CAS  Google Scholar 

  11. K. Fegy D. Luneau T. Ohm C. Paulsen P. Rey (1998) Angew. Chem. Int. Ed. 37 1270 Occurrence Handle10.1002/(SICI)1521-3773(19980518)37:9<1270::AID-ANIE1270>3.0.CO;2-6 Occurrence Handle1:CAS:528:DyaK1cXjs1egtL8%3D

    Article  CAS  Google Scholar 

  12. L.C. Li, D.Z. Liao, Z.H. Jiang and S.P. Yan, J. Chem. Soc., Dalton Trans., 1350 (2002)

  13. H.H. Lin S. Mohanta C.J. Lee H.H Wei (2003) Inorg. Chem. 42 1584 Occurrence Handle1:CAS:528:DC%2BD3sXhtFSjsb4%3D

    CAS  Google Scholar 

  14. K. Barthelet, D. Riou and G. Férey, Chem. Commun., 1492 (2002)

  15. J.F. Ma J. Yang G.L. Zheng L. Li J.F. Liu (2003) Inorg. Chem. 42 7531 Occurrence Handle1:CAS:528:DC%2BD3sXot1Smur4%3D

    CAS  Google Scholar 

  16. C. Cañada-Vilalta, M. Pink, G. Christou, J. Chem. Soc., Dalton Trans., 1121 (2003)

  17. Y.F. Zhou F.L. Jiang D.Q. Yuan B.L. Wu R.H. Wang Z.Z. Lin M.C. Hong (2004) Angew. Chem. Int. Ed. 43 5665 Occurrence Handle1:CAS:528:DC%2BD2cXps1KqtLo%3D

    CAS  Google Scholar 

  18. J. Tao, Y. Zhang, M.L. Tong, X.M. Chen, T. Yuen, C.L. Lin, X.Y. Huang and J. Li, Chem. Commun., 1342 (2002)

  19. C.B. Ma, C.N. Chen, Q.T. Liu, F. Chen, D.Z. Liao, L.C. Li and L.C. Sun, Eur. J. Inorg. Chem., 3316 (2004)

  20. L.C. Li D.Z. Liao Z.H. Jiang S.P. Yan (2002) Inorg. Chem. 41 421 Occurrence Handle1:CAS:528:DC%2BD3MXptFyisrY%3D

    CAS  Google Scholar 

  21. L.C. Li, Z.L. Liu, S.S. Turner, D.Z. Liao, Z.H. Jiang and S.P. Yan, Eur. J. Inorg. Chem., 62 (2003)

  22. L.C. Li D.Z. Liao Z.H. Jiang S.P. Yan (2004) Inorg. Chim. Acta 357 405 Occurrence Handle1:CAS:528:DC%2BD2cXmsFynsw%3D%3D

    CAS  Google Scholar 

  23. L.C. Li J. Li Z.H. Jiang D.Z. Liao S.P. Yan (2004) Chinese J. Struct. Chem. 23 519 Occurrence Handle1:CAS:528:DC%2BD2cXlt1aqsr4%3D

    CAS  Google Scholar 

  24. A. Caneschi, A. Dei and D. Gatteschi, Chem. Commun., 630 (1992)

  25. S. Bruni A. Aneschi F. Cariati C. Delfs A. Dei D. Gatteschi (1994) J. Am. Chem. Soc. 116 1388 Occurrence Handle10.1021/ja00083a026 Occurrence Handle1:CAS:528:DyaK2cXitVOhu74%3D

    Article  CAS  Google Scholar 

  26. H. Oshio T. Watanabe A. Ohto T. Ito U. Nagaschima (1994) Angew. Chem. Int. Ed. Engl. 33 670 Occurrence Handle10.1002/anie.199406701

    Article  Google Scholar 

  27. H. Oshio T. Watanabe A. Ohto T. Ito H. Masuda (1996) Inorg. Chem. 35 472 Occurrence Handle1:CAS:528:DyaK28Xjs1E%3D

    CAS  Google Scholar 

  28. H. Oshio T. Watanabe A. Ohto T. Ito T. Ikoma S. Tero-Kubota (1997) Inorg. Chem. 36 3014 Occurrence Handle1:CAS:528:DyaK2sXjslOkur8%3D

    CAS  Google Scholar 

  29. C.J. Lee, C.H. Huang, H.H. Wei, Y.R. Liu, G.H. Lee and Y. Wang, J. Chem. Soc. Dalton Trans., 171 (1998)

  30. H. Oshio M. Yamamoto N. Hoshino T. Ito (2001) Polyhedron 20 1621 Occurrence Handle10.1016/S0277-5387(01)00663-5 Occurrence Handle1:CAS:528:DC%2BD3MXksV2lsLg%3D

    Article  CAS  Google Scholar 

  31. C.J. Lee H.H. Wei (2000) Inorg. Chem. Acta 310 89 Occurrence Handle10.1016/S0020-1693(00)00273-5 Occurrence Handle1:CAS:528:DC%2BD3MXmtVeruw%3D%3D

    Article  CAS  Google Scholar 

  32. Y. Yamamoto, T. Suzuki and S. Kaizaki, J. Chem. Soc., Dalton Trans., 1566 (2001)

  33. Y. Yamamoto, T. Suzuki and S. Kaizaki, J. Chem. Soc., Dalton Trans., 2943 (2001)

  34. C. Stroh E. Belorizky P. Turek H. Bolvin R. Ziessel (2003) Inorg. Chem. 42 2938 Occurrence Handle10.1021/ic020484v Occurrence Handle1:CAS:528:DC%2BD3sXis1Kgtbk%3D

    Article  CAS  Google Scholar 

  35. H. Oshio M. Yamamoto T. Ito H. Kawauchi N. Koga T. Ikoma S. Tero-Kubota (2001) Inorg. Chem. 40 5518 Occurrence Handle1:CAS:528:DC%2BD3MXmvVSgsbY%3D

    CAS  Google Scholar 

  36. G. Francese F.M. Romero A. Neels H. Stoeckli-Evans S. Decurtins (2000) Inorg. Chem. 39 2087 Occurrence Handle10.1021/ic991236a Occurrence Handle1:CAS:528:DC%2BD3cXisFChu70%3D

    Article  CAS  Google Scholar 

  37. C.J. Lee H.H. Wei G.H. Lee Y. Wang (2000) Inorg. Chem. Commun. 3 690 Occurrence Handle10.1016/S1387-7003(00)00178-7 Occurrence Handle1:CAS:528:DC%2BD3cXovFelsbs%3D

    Article  CAS  Google Scholar 

  38. M.S. Davis K. Morokuma R.W. Kreilick (1972) J. Am. Chem. Soc. 94 5588 Occurrence Handle1:CAS:528:DyaE38XltVShtbc%3D

    CAS  Google Scholar 

  39. G.M. Sheldrick (1997) SHELXS 97, Program for the Solution of Crystal Structure University of Göttingen Germany

    Google Scholar 

  40. G.M. Sheidrick (1997) SHELXL 97, Program for the Refinement of Crystal Structure University of Göttingen Germany

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Nankai University, Weijin Road 94, Tianjin, 300071, P.R. China

    Shu-Ping Wang, Dong-Zhao Gao, Dai-Zheng Liao, Zong-Hui Jiang & Shi-Ping Yan

  2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P. R. China

    Zong-Hui Jiang

Authors
  1. Shu-Ping Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dong-Zhao Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dai-Zheng Liao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zong-Hui Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Shi-Ping Yan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zong-Hui Jiang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, SP., Gao, DZ., Liao, DZ. et al. Two Novel Diamagnetic-metal Coordination Polymers of Nitronyl Nitroxide Radical Incorporating Isophthalate Bridges. Transition Met Chem 31, 214–219 (2006). https://doi.org/10.1007/s11243-005-6396-x

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-005-6396-x

Keywords

Search

Navigation