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N-(salicylidene)nitrosophenylglycine Schiff base as NOOO-donor towards transition metal ions

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Abstract

A new tetradentate NOOO-donor ligand, N-(salicylidene)nitrosophenylglycine (H2snpg) has been designed, synthesized and structurally characterized. Copper(II), nickel(II), cobalt(II), manganese(II) and zinc(II) complexes of H2snpg have been prepared for the first time. The authenticities of the ligand and its metal complexes have been established on the basis of elemental analyses, molar conductance measurements, magnetic properties, spectral (i.r., 1H-n.m.r., u.v.–vis. and mass) studies. The i.r. spectral studies of all the complexes exhibit a similar feature about the ligating nature of the ligand to the metal ions and revealed that the ligand has coordinated through the carbonyl oxygen, azomethine nitrogen, nitroso oxygen and deprotonated hydroxyl oxygen. The molar conductance data suggest them to be non-electrolytes. The antimicrobial activity of all the compounds was studied against Escherichia coli, Bacillus cirroflagellosus, Aspergillus niger and Candida albicans. All the complexes have shown a moderate to high fungal activity compared to the ligand.

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References

  1. S.A. Sallam M.I. Ayad J. Korean (2003) Chem. Soc. 47 IssueID3 199 Occurrence Handle1:CAS:528:DC%2BD3sXltFersL8%3D

    CAS  Google Scholar 

  2. M.R. Mahmoud A.K. El-Shafei A.M. Abdel-Mawgoud (1982) J. Chem. Tech. Biotechnol. 32 933 Occurrence Handle1:CAS:528:DyaL3sXit1Krt7c%3D

    CAS  Google Scholar 

  3. L.G. MacDonald D.H. Brown J.H. Morris W.E. Smith (1982) Inorg. Chim. Acta 67 7 Occurrence Handle1:CAS:528:DyaL38XltlOlt7Y%3D Occurrence Handle10.1016/S0020-1693(00)85032-X

    Article  CAS  Google Scholar 

  4. M.T.H. Tarafder A.R. Khan (1997) J. Ind. Chem. Soc. 74 489 Occurrence Handle1:CAS:528:DyaK2sXkvVaht7c%3D

    CAS  Google Scholar 

  5. L. Casella, M. Gullotti and E. Melani, J. Chem. Soc. Perkin Trans. I., 18227 (1982)

  6. J.W. Pyrz A.I. Roe L.J. Stem L. Que SuffixJr. (1985) J. Am. Chem. Soc. 107 614 Occurrence Handle1:CAS:528:DyaL2MXlsl2rsg%3D%3D Occurrence Handle10.1021/ja00289a013

    Article  CAS  Google Scholar 

  7. A.E. Martell B. Szpoganicz (1989) Inorg. Chem. 28 4199 Occurrence Handle1:CAS:528:DyaL1MXmt1Shtrw%3D Occurrence Handle10.1021/ic00322a006

    Article  CAS  Google Scholar 

  8. T.M. Aminabhavi N.S. Biradar S.B. Patil V.L. Roddabasanagoudar W.E. Rudzinski (1985) Inorg. Chim. Acta 107 231 Occurrence Handle1:CAS:528:DyaL28XksVaru7c%3D Occurrence Handle10.1016/S0020-1693(00)82293-8

    Article  CAS  Google Scholar 

  9. M.G. Weller U. Weser (1982) J. Am. Chem. Soc. 104 3752 Occurrence Handle1:CAS:528:DyaL38XksFGjt70%3D Occurrence Handle10.1021/ja00377a049

    Article  CAS  Google Scholar 

  10. R. H. Holm, in Inorganic Biochemistry, G. L. Eichhorn (Ed.), Elsevier, New York, 1973

  11. Y. Nakao K. Sakuraj K. Nakahara (1967) Bull. Chem. Soc. Jpn. 40 1536 Occurrence Handle1:CAS:528:DyaF2sXkvVOgs7o%3D Occurrence Handle10.1246/bcsj.40.1536

    Article  CAS  Google Scholar 

  12. Casella L., Pasini A., Ugo R., Visca M. (1980) J. Chem. Soc. Dalton. Trans. 1655

  13. L. Casella M. Gulloti G. Pacchioni (1982) J. Am. Chem. Soc. 104 2386 Occurrence Handle1:CAS:528:DyaL38Xhslegs74%3D Occurrence Handle10.1021/ja00373a010

    Article  CAS  Google Scholar 

  14. R. Shanthi K.S. Nagaraja M.R. Udupa (1987) Inorg. Chim. Acta 133 211 Occurrence Handle1:CAS:528:DyaL1cXhsVajtLc%3D Occurrence Handle10.1016/S0020-1693(00)87768-3

    Article  CAS  Google Scholar 

  15. L. Casella M. Gulloti (1983) J. Am. Chem. Soc. 105 803 Occurrence Handle1:CAS:528:DyaL3sXovFynsw%3D%3D Occurrence Handle10.1021/ja00342a026

    Article  CAS  Google Scholar 

  16. D. Yang S.R. Tannenbaum G. Büchi G.C.M. Lee (1984) Carcinogenesis. 5 IssueID10 1219 Occurrence Handle1:CAS:528:DyaL2MXksFOl

    CAS  Google Scholar 

  17. R.W. Darbeau R.E. Gibble R.S. Pease D.E. Bridges L.M. Siso D.J. Heurtin (2001) J. Chem. Soc., Perkin Trans. 2 1084

    Google Scholar 

  18. A.I. Vogel (1969) A Text Book of Quantitative Inorganic Analysis Longman London

    Google Scholar 

  19. T.M. Aminabhavi N.S. Biradar S.B. Patil D.E. Hoffman N.N. Biradar (1987) Inorg. Chim. Acta 135 139 Occurrence Handle1:CAS:528:DyaL1cXjsl2kuw%3D%3D Occurrence Handle10.1016/S0020-1693(00)83278-8

    Article  CAS  Google Scholar 

  20. M. Mashima (1962) Bull. chem. Soc. Japan 35 332 Occurrence Handle1:CAS:528:DyaF38XktVyktbs%3D Occurrence Handle10.1246/bcsj.35.332

    Article  CAS  Google Scholar 

  21. H. Feuer, The Chemistry of Nitro and Nitroso Groups, Part 1, Intersciences Publishers, John Wiley and Sons, 1969

  22. Y. Nishida S. Kida (1979) Coord. Chem. Rev. 27 275 Occurrence Handle1:CAS:528:DyaE1MXks1Ggt7s%3D Occurrence Handle10.1016/S0010-8545(00)82069-X

    Article  CAS  Google Scholar 

  23. E.P. Wyrzykiewicz (1998) J. Het. Chem. 35 381 Occurrence Handle1:CAS:528:DyaK1cXjsVSrsrw%3D Occurrence Handle10.1002/jhet.5570350221

    Article  CAS  Google Scholar 

  24. D.N. Sathyanarayana, Electronic Absorption Spectroscopy and Related Techniques, Orient Longman Limited, © Universities Press (India) Limited, 2001

  25. T. Miyazawa T. Shimanouchi S. Mizushima (1958) J. Chem. Phys. 29 64

    Google Scholar 

  26. A.B.P. Lever (1968) Inorg. Electronic Spectroscopy Elsevier New York

    Google Scholar 

  27. B.J. Hathaway D.E. Billing (1970) Coord. Chem Rev. 5 143 Occurrence Handle1:CAS:528:DyaE3cXkvFCitbw%3D Occurrence Handle10.1016/S0010-8545(00)80135-6

    Article  CAS  Google Scholar 

  28. R.L. Farmer F.L. Urbach (1974) Inorg. Chem. 13 587 Occurrence Handle1:CAS:528:DyaE2cXptVCqsg%3D%3D Occurrence Handle10.1021/ic50133a017

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Karnatak University, Dharwad, 580 003, India

    Kalagouda B. Gudasi, Manjula S. Patil, Ramesh S. Vadavi, Rashmi V. Shenoy & Siddappa A. Patil

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  1. Kalagouda B. Gudasi
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  2. Manjula S. Patil
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  3. Ramesh S. Vadavi
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  4. Rashmi V. Shenoy
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  5. Siddappa A. Patil
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Correspondence to Kalagouda B. Gudasi.

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Gudasi, K.B., Patil, M.S., Vadavi, R.S. et al. N-(salicylidene)nitrosophenylglycine Schiff base as NOOO-donor towards transition metal ions. Transition Met Chem 31, 986–991 (2006). https://doi.org/10.1007/s11243-006-0094-1

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