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Synthesis and reactivity of N,N-bis(diphenylphosphino)dimethylaniline compounds

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Abstract

New chalcogenides and complexes of N,N-bis(diphenylphosphino)dimethylanilines were prepared by the reaction of N,N-bis(diphenylphosphino)dimethylaniline ligands with aqueous H2O2, elemental S and Se and transition metal complexes based on Cu, Pd and Pt. All the new compounds have been characterised by spectroscopy and the molecular structures of the three complexes of N,N-bis(diphenylphosphino)dimethylanilines have been determined by X-ray crystallography.

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Authors and Affiliations

  1. Department of Chemistry, University of Dicle, Diyarbakir, 21280, Turkey

    Nermin Biricik, Feyyaz Durap & Bahattin Gümgüm

  2. Institut de Chimie Moleculaire et Biologique, Ecole Polytecnique Federale de Lausanne (EPFL), Lausanne, CH-1015, Switzerland

    Zhaofu Fei & Rosario Scopelliti

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  1. Nermin Biricik
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  2. Feyyaz Durap
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  3. Bahattin Gümgüm
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  4. Zhaofu Fei
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  5. Rosario Scopelliti
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Correspondence to Nermin Biricik.

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Biricik, N., Durap, F., Gümgüm, B. et al. Synthesis and reactivity of N,N-bis(diphenylphosphino)dimethylaniline compounds. Transition Met Chem 32, 877–883 (2007). https://doi.org/10.1007/s11243-007-0231-5

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  • DOI: https://doi.org/10.1007/s11243-007-0231-5

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